화학공학소재연구정보센터
Applied Surface Science, Vol.464, 140-145, 2019
Fabrication of superamphiphobic Cu surfaces using hierarchical surface morphology and fluorocarbon attachment facilitated by plasma activation
A simple and robust method for fabrication of superamphiphobic surfaces by template-free chemical deposition of Cu micro-cone arrays, followed by air plasma activation and room-temperature treatment in tridecafluoro1,1,2,2- tetrahydrooctyl trichlorosilane (FTS) is reported in this paper. After only treatment with 15 min of FTS, a water contact angle of 166.1 degrees and an oil (diiodomethane, CH2I2) contact angle of 160.5 degrees are reached on the Cu surfaces. The highest oil contact angle of 168.1 degrees is achieved after 1 h treatment with FTS. Such surfaces also display enhanced corrosion resistance due to the combination of the FTS layer and air pockets which prevent ion diffusion to the internal copper.