Electroactive 3D conductive collectors of beta-NiS@Ni3S2 are obtained from the in-situ conversion of Ni foams and exhibit unique hierarchical pine twig-like microstructure, in which the beta-NiS nanorod arrays are uniformly supported on hollow Ni3S2 skeletons. Then the mesoporous NiO nanosheet arrays are grown successfully on the surface of beta-NiS nanorods via a facile hydrothermal method and the following calcination, forming hierarchical NiO@beta-NiS@Ni3S2 composites. When directly used as anodes for lithium-ion batteries (LIBs), the obtained composites deliver superior lithium storage properties with a considerable reversible capacity of 498.5 mAh g(-1) (calculated by the mass of the whole anode including substrate) after 100 cycles and excellent rate capability, holding a great promise as free-standing integrated anodes for high-performance LIBs. The remarkable electrochemical performance could be attributed to the well-designed 3D hierarchical heterostructures and the synergy effect from the integration of NiO, beta-NiS and Ni3S2. Importantly, the beta-NiS@Ni3S2 conductive collectors also possess electrochemical activity and make a significant contribution in lithium storage.