The tetrasulfur tetranitrogen (S4N4) compound has attracted attention for its unusual "extreme cradle" structure. We report here the nature and magnitude of noncovalent interactions of S4N4 with model pi-ring systems. The sigma-hole of sulfur atom interacts with the pi electron density of benzene and naphthalene rings. The interaction energy of S4N4 with three naphthalene rings is similar to 20.0 kcal/mol. The fluorinated benzene rings showed weaker interaction with S4N4 compared to unsubstituted benzene rings. The energy decomposition analysis (EDA) reveals the larger contribution of dispersion energy in such complexes.