화학공학소재연구정보센터
Chinese Journal of Chemical Engineering, Vol.26, No.10, 2102-2111, 2018
Investigation on and industrial application of degrading of methanol feed in methanol to propylene process
At present, methanol to propylene (MTP) technology developed by Lurgi Company is adopted for commercial plants and refined methanol with the purity >=.99.85 wt% is required as the feed of MTP unit in Lurgi's technology. Therefore, high energy cost for refined methanol production is one of the bottlenecks to improve the economy of MTP technology. Reducing the grade of feed refined methanol may be an effective method to save energy and reduce operation costs in MTP process. In this work, experiments and process simulation were carried out to investigate the influence and feasibility of degrading the methanol feed. Experiments were conducted to investigate the influence of crude methanol feed on conversion and selectivity of MTP reaction as well as the performance of ZSM-5 catalyst. The experimental results showed that degrading the methanol feed had no obvious influence on the conversion and selectivity of MTP reactions and the catalyst deactivation was caused by the carbon accumulation and metals deposition on the active sites. The process simulation results showed that the influence on the conversion and selectivity as well as the stream load of MI? process was negligible if 98mol% methanol was used as feed. Finally, industrial experiments were conducted by adjusting the operation parameters to degrade of feed methanol of the commercial 500 kt.a(-1) MTP unit of Ningmei Group in China. The results of industrial application illustrated that annually 180 kt fuel coal and 150 kt desalted water as well as1770 MW.h(-1) electricity would be saved when the water content increased from 0.01% to 0.4%. This work has identified the feasibility to improve MTP technology by degrading the methanol feed. (C) 2018 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.