It is of great significance to develop high-efficiency and low-cost electrocatalysts towards oxygen evolution reaction (OER) due to their critical role in the electrochemical water splitting to produce H-2 fuel. Herein, a well-controlled hierarchical structured bimetallic electrocatalyst of Co3O4@Ni2P-CoP/NF is constructed via phosphating and carbonating Co3O4 nanowires template-directed fabrication Ni-substituted ZIF-67 arrays onto a 3D Ni foam substrate. The as-obtained hierarchical structured nano-material displays superior electrocatalytic performance with a small overpotential of 298 mV required to achieve the current density of 50 mAcm(-2) and reveals high electrocatalytic activity with long-term durability after continuously working for 40 h in 1.0 M KOH. The good performance of the material for OER can be attributed to the synergistic effect of optimized hierarchical structure, partial substitution of Ni for Co, high porosity and N, P-codoping. (C) 2018 Elsevier Ltd. All rights reserved.