화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.482, 126-133, 2019
Extending application of Dehaghani Association Equation of State for Modeling Phase Behavior of Water-Alcohol Systems
This paper concerns extending applicability of Dehaghani association equation of state (in short DA-EOS) to model non-ideality in phase behavior caused by hydrogen bonding. Advantageously, this equation only needs two and one parameters to treat self- and cross association, respectively, which were determined for methanol/water and ethanol/water mixture in this study. In this respect, DA was coupled with PR and SRK EOS to account for physical interaction between molecules. Notably, DA-PR persistently provides more accurate prediction than DA-SRK for both aqueous methanol and ethanol solutions. (C) 2018 Elsevier B.V. All rights reserved.