As known, a good support enhances the activity and durability of any catalyst. In the current study, polypyrrole (PPY)/nanocomposite (MWCNTs and Al2O3) films were fabricated by electrochemical polymerization of pyrrole solution with a certain amount of nanoparticles on titanium substrates and were used as new support materials for Pt catalyst. The modified electrodes were characterized by Fourier transform infrared (FT-IR) spectroscopy, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis (EDX) techniques. High catalytic activity and long-time stability toward methanol oxidation of Pt/PPY MWNTs-alpha Al2O3 catalyst have also been verified by cyclic voltammetry results and chronoamperometric response measurements. This catalyst exhibits a vehemently high current density (345.03 mA cm(-2)) and low peak potential (0.74 v) for methanol oxidation. Other electrochemical measurements (electrochemical impedance spectroscopy (EIS), CO stripping voltammetry and Tafel test) clearly confirmed that Pt/PPY-MWNTs-alpha Al2O3/Ti electrode has a better performance toward methanol oxidation compared to the other electrodes and that can be used as a promising electrode material for application in direct methanol fuel cells (DMFCs). (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.