화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.43, No.45, 21060-21069, 2018
Transport equations for reaction rate in laminar and turbulent premixed flames characterized by non-unity Lewis number
Transport equations for (i) the rate W of product creation and (ii) its Favre-averaged value W are derived from the first principles by assuming that W depends solely on the temperature and mass fraction of a deficient reactant in a premixed turbulent flame characterized by the Lewis number Le different from unity. The right hand side of the transport equation for W involves seven unclosed terms, with some of them having opposite signs and approximately equal large magnitudes when compared to the left-hand-side terms. Accordingly, separately closing each term does not seem to be a promising approach, but a joint closure relation for the sum (T-Sigma) over bar of the seven terms is sought. For this purpose, theoretical and numerical investigations of variously stretched laminar premixed flames characterized by Le <1 are performed and the linear relation between T-Sigma integrated along the normal to a laminar flame and a product of (i) the consumption velocity u, and (ii) the stretch rate u, evaluated in the flame reaction zone is obtained. Based on this finding and simple physical reasoning, a joint closure relation of <(T-Sigma)over bar> (rho Ws) over bar is hypothesized, where p is the density ands is the stretch rate. The joint closure relation is tested against 3D DNS data obtained from three statistically 1D, planar, adiabatic, premixed turbulent flames in the case of a single-step chemistry and Le = 0.34, 0.6, or 0.8. In all three cases, the agreement between T2 and pWS extracted from the DNS is good with exception of large ((c) over bar> 0.4) values of the mean combustion progress variable c in the case of Le = 0.34. The developed linear relation between (T-Sigma) over bar and (rho Ws) over bar helps to understand why the leading edge of a premixed turbulent flame brush can control its speed. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.