화학공학소재연구정보센터
Journal of Food Engineering, Vol.241, 33-40, 2019
Comparative study on crystallization behaviors of physical blend- and interesterified blend-based special fats
Crystallization behavior of special fats has a crucial influence on their physical properties. A comparative study was carried out on the crystallization characteristics of physical blend- and interesterifled blend-based fast frozen special fats (PBSF and IBSF). The content of trisaturated TAGs (SSS) decreased from 27.3% for PBSF to 12.5% for IBSF. At 0-45 degrees C, the SFC of PBSF and IBSF varied from 60.2% to 16.3% and from 53.1% to 2.9%, respectively. XRD results indicated that PBSF and IBSF had beta' and beta crystals with double chain length structures, but IBSF had moreP crystal content. Isothermal and non-isothermal crystallization kinetics studied by pNMR and DSC revealed that the nucleation and growth mechanism of PBSF and IBSF was different during crystallization. For IBSF, there were a large amount of spherical crystals with small size present in the crystal network. However, rod-like crystals with big size were distributed throughout the crystal network of PBSF.