This work presents the synthesis of the noble nanocomposites of silica-coated calcium copper titanate-graphene (CCTO@SiO2-GO) by the established sol-gel method. This paper showed the decoration of CCTO@SiO2 NPs on the surface of graphene oxide and how the decoration/attachment depends on various environmental and instrumental factors like sonication time, stirring rate, centrifugation rpm and the thickness of silica shell coated on CCTO NPs. The prepared CCTO@SiO2-GO composites were characterized by suitable characterization techniques. FESEM and TEM confirmed the morphological study of nanocomposites and how the CCTO@SiO2 NPs are attached to the surface of GO sheet. FTIR has shown the presence of O-H, N-C groups which help in the formation of types of bonds between CCTO@SiO2 NPs and GO. This work further revealed an excellent result of a dielectric study, indicating that the best-decorated CCTO@SiO2 NPs over the surface of the GO sheet cause the increment of dielectric constant epsilon from 10(2) up to 10(5). Meanwhile, this study also suggested high loss epsilon up to 10(6) at a lower frequency, i.e. 20Hz at RT which can be useful for microelectronic devices. This variance of dielectrics is due to the effect of polarization and decoration of CCTO@SiO2 NPs over the GO sheets. As the frequency increases from 20Hz to 2MHz, the dielectric constant epsilon, as well as the loss of epsilon, reached up to 10(2) values for the highest decorated material. Our study also clearly explained a uniform variation in dielectric constant ranges from 1x10(2) to 1.5x10(4) at a different temperature range from room temperature to 560 degrees C with a frequency range of 3x10(4) Hz to 2x10(6) Hz, and the value varies accordingly with the synthesis method.