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Journal of Microencapsulation, Vol.35, No.6, 513-521, 2018
Formation of essential oil containing microparticles comprising a hydrogenated vegetable oil matrix and characterisation thereof
Microparticles with different essential oil concentrations 0, 75, 150, 225 and 300gkg(-1), (g of essential oil per kg of microparticles), were produced by dispersing the essential oils within a hydrogenated vegetable fat matrix and forming spherical solid particles by spray-chilling. Size distribution, flowability, surface structure, essential oil recovery, melting properties and crystallinity of the microparticles were determined. With over 225gkg(-1) essential oil the microparticle surface became stickier, their flowability was reduced and the size distribution broadened. Gas chromatography showed that the essential oil recovery was always above 85% v/v. The surface structure of the microparticles was strongly affected by the essential oil concentration being smooth (225gkg(-1)), comprising round-shaped dumps (300gkg(-1)) or showing fat blooming (0, 75, 150gkg(-1)). With essential oil, the formation of the beta-polymorphic form of the triglycerides was supported leading to changes in the melting behaviour and the crystalline structure.
Keywords:Essential oils;microencapsulation;spray-chilling;hydrogenated vegetable fat;melting behaviour;crystallinity