화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.166, No.1, D3219-D3225, 2018
Review-Ruthenium as Diffusion Barrier Layer in Electronic Interconnects: Current Literature with a Focus on Electrochemical Deposition Methods
Ruthenium is one of the most promising candidates to replace tantalum and titanium based diffusion barrier layers in microelectronics. Its unique properties allow the deposition of ultrathin layers with controlled thickness by means of a wide variety of different techniques. Ruthenium barriers are characterized by good thermal stability, low resistivity and great adherence. Moreover, the copper filling deposited during the Damascene process can be directly applied on the barrier without the need of a seed layer. As a consequence of the industrial interest in developing new ruthenium based interconnects technologies, a significant literature has been produced in the last few years. The scope of the present work is to collect and analyze the literature on the topic, investigating in this way the technologies developed in the past and the current development stage of ruthenium based barrier layers. Due to their multiple advantages, a special focus is devoted to the manufacturing of ruthenium diffusion limiters by mean of wet electrochemical processes. (C) The Author(s) 2018. Published by ECS.