Graphene oxide as a potential nanocarrier for Zn(II) to fabricate a dual-functional active/passive protection; sorption/desorption characteristics and electrochemical evaluation

Mojtaba Kasaeian; Ebrahim Ghasemi; Bahram Ramezanzadeh; Mohammad Mahdavian

Journal of Industrial and Engineering Chemistry, Vol.73, 162-174, May, 2019

DOI10.1016/j.jiec.2019.01.019 Export Citation

Graphene oxide as a potential nanocarrier for Zn(II) to fabricate a dual-functional active/passive protection; sorption/desorption characteristics and electrochemical evaluation

Mojtaba Kasaeian^{1, 2}, Ebrahim Ghasemi^{1, 3, †}, Bahram Ramezanzadeh², and Mohammad Mahdavian^{2, †}

¹Inorganic Pigment and Glazes Department, Institute for Color Science and Technology, Tehran, Iran
²Surface Coating and Corrosion Department, Institute for Color Science and Technology, Tehran, Iran
³Center of Excellence for Color Science and Technologies, Institute for Color Science and Technology (CECST), Tehran, Iran

E-mail:,

Herein, we demonstrated a facile non-covalent functionalization route to exploit the GO sheets as an efficient carrier for high loading of Zn(II) corrosion inhibitor with the controllable slow release. The Zn(II) intercalated GO exhibited good compatibility with epoxy matrix stemming from the chemical and structural alterations as confirmed by Raman analysis along with XPS, FE-SEM and HRTEM. The kinetics of Zn(II) release from the GO carrier revealed the consistency of experimental data with the Higuchi model. EIS combined with cathodic disbondment tests results proved the dual-function active/passive corrosion mitigation of Zn(II) intercalated GO-Epoxy system.

Keywords:Non-covalent functionalization;Graphene oxide;Nanocarrier;EIS;Cathodic disbondment

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Chowdhury I, Duch MC, Mansukhani ND, Hersam MC, Bouchard D, Environ. Sci. Technol., 47 (2013)
Gallivan JP, Dougherty DA, Proc. Natl. Acad. Sci. U. S. A., 96, 9459 (1999)
Dougherty DA, Accounts Chem. Res., 46, 885 (2013)
Kharisov BI, Kharissova OV, Dimas AV, De La Fuente IG, Mendez YP, J. Coord. Chem., 69, 1125 (2016)
Park S, Lee KS, Bozoklu G, Cai W, Nguyen SBT, Ruoff RS, ACS Nano, 2, 572 (2008)

[Referenced By]

[1] Visser P, Terryn H, Mol JMC, Corrosion Sci., 140, 272 (2018)

[2] Galvao TLP, Sousa I, Wilhelm M, Carneiro J, Oprsal J, Kukackova H, Spacek V, Maia F, Gomes JRB, Tedim J, Ferreira MGS, Chem. Eng. J., 341, 526 (2018)

[3] Huang Y, Deng L, Ju P, Huang L, Qian H, Zhang D, Li X, Terryn HA, Mol JMC, ACS Appl. Mater. Interfaces, 10, 23369 (2018)

[4] Liu C, Qiu S, Du P, Zhao H, Wang L, Nanoscale, 10, 8115 (2018)

[5] Yang Y, Hou H, Zou G, Shi W, Shuai H, Li J, Ji X, Nanoscale, 11, 16 (2019)

[6] Rostamnia S, Doustkhah E, Karimi Z, Amini S, Luque R, ChemCatChem, 7, 1678 (2015)

[7] Rostamnia S, Doustkhah E, Golchin-Hosseini H, Zeynizadeh B, Xin H, Luque R, Catal. Sci. Technol., 6, 4124 (2016)

[8] Rostamnia S, Doustkhah E, Zeynizadeh B, J. Mol. Catal. A-Chem., 416, 88 (2016)

[9] Deng S, Cherian CT, Liu XI, Tan HR, Yeo LH, Yu X, Rusydi A, Chowdari BVR, Fan HM, Sow CH, Chem.: Eur J., 20, 12444 (2014)

[10] Lu H, Zhang S, Li W, Cui Y, Yang T, ACS Appl. Mater. Interfaces, 9, 4034 (2017)

[11] Lee W, Lee JU, Jung BM, Byun JH, Yi JW, Lee SB, Kim BS, Carbon, 65, 296 (2013)

[12] Parhizkar N, Ramezanzadeh B, Shahrabi T, J. Electrochem. Soc., 164(14), C1044 (2017)

[13] Liu C, Du P, Zhao H, Wang L, ACS Appl. Nano Mater., 1, 1385 (2018)

[14] Li J, Cui J, Yang J, Ma Y, Qiu H, Yang J, Prog. Org. Coat., 99, 443 (2016)

[15] Cui MJ, Ren SM, Zhao HC, Xue QJ, Wang LP, Chem. Eng. J., 335, 255 (2018)

[16] Dutta D, Ganda ANF, Chih JK, Huang CC, Tseng CJ, Su CY, Nanoscale, 10, 12612 (2018)

[17] Logpriya S, Bhuvaneshwari V, Vaidehi D, SenthilKumar RP, Malar RSN, Sheetal BP, Amsaveni R, Kalaiselvi M, J. Nanostructure Chem., 8, 301 (2018)

[18] Khalili MS, Zare K, Moradi O, Sillanpaa M, J. Nanostruct. Chem., 8, 103 (2018)

[19] Moradi O, Aghaie M, Zare K, Monajjemi M, Aghaie H, J. Hazard. Mater., 170(2-3), 673 (2009)

[20] Moradi O, Zare K, Monajjemi M, Yari M, Aghaie H, Fullerenes Nanotubes Carbon Nanostruct., 18, 285 (2010)

[21] Priyadarsini S, Mohanty S, Mukherjee S, Basu S, Mishra M, J. Nanostruct. Chem., 8, 123 (2018)

[22] Elnaggar EM, Kabel KI, Farag AA, Al-Gamal AG, J. Nanostruct. Chem., 7, 75 (2017)

[23] Rouhollahi A, Fazlolahzadeh O, Dolati A, Ghahramanifard F, J. Nanostruct. Chem., 8, 139 (2018)

[24] Zaaba NI, Foo KL, Hashim U, Tan SJ, Liu WW, Voon CH, Procedia Eng., 469 (2017).

[25] Sitko R, Turek E, Zawisza B, Malicka E, Talik E, Heimann J, Gagor A, Feist B, Wrzalik R, Dalton Trans., 42, 5682 (2013)

[26] Wang H, Yuan X, Wu Y, Huang H, Zeng G, Appl. Surf. Sci., 279, 432 (2013)

[27] Parlayici S, Eskizeybek V, Avcı A, Pehlivan E, J. Nanostruct. Chem., 5, 255 (2015)

[28] Moradi O, Zare K, Fullerenes Nanotubes Carbon Nanostruct., 19, 628 (2011)

[29] Yari M, Rajabi M, Moradi O, Yari A, Asif M, Agarwal S, Gupta VK, J. Mol. Liq., 209, 50 (2015)

[30] Yari M, Norouzi M, Mahvi AH, Rajabi M, Yari A, Moradi O, Tyagi I, Gupta VK, Desalin. Water Treat., 57, 11195 (2016)

[31] Dash S, Murthy PN, Nath L, Chowdhury P, Acta Pol. Pharm., 67, 217 (2010)

[32] Higuchi T, J. Pharm. Sci., 52, 1145 (1963)

[33] Hixson AW, Crowell JH, Ind. Eng. Chem., 23, 1160 (1931)

[34] Korsmeyer RW, Gurny R, Doelker E, Buri P, Peppas NA, Int. J. Pharm., 15, 25 (1983)

[35] Shih CJ, Lin SC, Sharma R, Strano MS, Blankschtein D, Langmuir, 28(1), 235 (2012)

[36] Fan W, Jiang XH, Yang W, Geng Z, Huo MX, Liu ZM, Zhou H, Sci. Total Environ., 511, 509 (2015)

[37] Wu L, Liu L, Gao B, Munoz-Carpena R, Zhang M, Chen H, Zhou ZH, Wang H, Langmuir, 29(49), 15174 (2013)

[38] Konkena B, Vasudevan S, J. Phys. Chem. Lett., 3, 867 (2012)

[39] Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45, 10454 (2011)

[40] Chowdhury I, Duch MC, Mansukhani ND, Hersam MC, Bouchard D, Environ. Sci. Technol., 47 (2013)

[41] Gallivan JP, Dougherty DA, Proc. Natl. Acad. Sci. U. S. A., 96, 9459 (1999)

[42] Dougherty DA, Accounts Chem. Res., 46, 885 (2013)

[43] Kharisov BI, Kharissova OV, Dimas AV, De La Fuente IG, Mendez YP, J. Coord. Chem., 69, 1125 (2016)

[44] Park S, Lee KS, Bozoklu G, Cai W, Nguyen SBT, Ruoff RS, ACS Nano, 2, 572 (2008)