화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.73, 233-240, May, 2019
DOI10.1016/j.jiec.2019.01.029  Export Citation
Characteristics and mechanism of Pb(II) adsorption/desorption on GO/r-GO under sulfide-reducing conditions
Jianfeng Zhang†, Xiaodan Xie, Cheng Liang, Weihuang Zhu, and Xiaoguang Meng1
  • Shaanxi Key Laboratory of Environmental Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
  • 1Center for Environmental Systems, Stevens Institute of Technology, Hoboken NJ 07030, USA
E-mail:
Compared with graphene oxide (GO), r-GO (the reduced form) has a lower adsorption capacity for heavy metal ions and, therefore, generates concern over the release of adsorbed contaminants when GO adsorbent is discharged into a reducing environment. This study reveals that the maximum adsorption capacity of Pb(II) on GO and r-GO was 937.65 and 92.99 mg g?1 respectively. GO was reduced to r-GO by sulfide, causing 2.59?6.46% of the adsorbed Pb(II) to be released and was stably dispersed as a Pb(II)-oxidative debris (OD) complex. Our results provide valuable information about heavy metal transportation in environments containing GO under different redox conditions.
Keywords:Graphene oxide;Adsorption/desorption characteristic;Pb(II);Sulfide-reduced graphene oxide
  1. Geim AK, Science, 324(5934), 1530 (2009)
  2. Stankovich S, Dikin DA, Dommett GH, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS, Nature, 442(7100), 282 (2006)
  3. Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)
  4. Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39(1), 228 (2010)
  5. Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4(8), 4806 (2010)
  6. Lee DW, De Los Santos L, Seo JW, Felix LL, Bustamante A, Cole JM, Barnes CHW, J. Phys. Chem. B, 114(17), 5723 (2010)
  7. Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45(24), 10454 (2011)
  8. Goel J, Kadirvelu K, Rajagopal C, Garg VK, J. Hazard. Mater., 125(1-3), 211 (2005)
  9. Machida M, Mochimaru T, Tatsumoto H, Carbon, 44(13), 2681 (2006)
  10. Gercel O, Gercel HF, Chem. Eng. J., 132(1-3), 289 (2007)
  11. Yang ST, Chang YL, Wang HF, Liu GB, Chen S, Wang YW, Liu YF, Cao AN, J. Colloid Interface Sci., 351(1), 122 (2010)
  12. Sun Y, Wang Q, Chen C, Tan X, Wang X, Environ. Sci. Technol., 46(11), 6020 (2012)
  13. Sitko R, Turek E, Zawisza B, Malicka E, Talik E, Heimann J, Gagor A, Feist B, Wrzalik R, Dalton Trans., 42(16), 5682 (2013)
  14. Lim JY, Mubarak NM, Abdullah EC, Nizamuddin S, Khalid M, Inamuddin, J. Ind. Eng. Chem., 66, 29 (2018)
  15. Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
  16. Pei S, Cheng HM, Carbon, 50(9), 3210 (2012)
  17. Shin HJ, Kim KK, Benayad A, Yoon SM, Park HK, Jung IS, Jin MH, Jeong HK, Kim JM, Choi JY, Lee YH, Adv. Funct. Mater., 19(12), 1987 (2009)
  18. Ferna’ndez-Merino MJ, Guardia L, Paredes J, Villar-Rodil S, Soli’s-Ferna’ndez P, Marti’nez-Alonso A, Tascon J, J. Phys. Chem. C, 114(14), 6426 (2010)
  19. McAllister MJ, Li JL, Adamson DH, Schniepp HC, Abdala AA, Liu J, Herrera-Alonso M, Milius DL, Car R, Prud’homme RK, Chem. Mater., 19(18), 4396 (2007)
  20. Hassan HM, Abdelsayed V, Abd El Rahman SK, AbouZeid KM, Terner J, El-Shall MS, Al-Resayes SI, El-Azhary AA, J. Mater. Chem., 19, 3832 (2009)
  21. Zhu Y, Murali S, Stoller MD, Velamakanni A, Piner RD, Ruoff RS, Carbon, 48(7), 2118 (2010)
  22. Wang G, Yang J, Park J, Gou X, Wang B, Liu H, Yao J, J. Phys. Chem. C, 112(22), 8192 (2008)
  23. Chen W, Yan L, Bangal P, J. Phys. Chem. C, 114(47), 19885 (2010)
  24. Salas EC, Sun Z, Luttge A, Tour JM, ACS Nano, 4(8), 4852 (2010)
  25. Ye S, Zeng G, Wu H, Zhang C, Dai J, Liang J, Yu J, Ren X, Yi H, Cheng M, Crit. Rev. Biotechnol., 37(8), 1 (2017)
  26. Ye S, Zeng G, Wu H, Zhang C, Liang J, Dai J, Liu Z, Xiong W, Wan J, Xu P, Crit. Rev. Environ. Sci. Technol., 47(19) (2017)
  27. Wu H, Cui L, Zeng G, Jie L, Jin C, Xu J, Dai J, Li X, Liu J, Ming C, Crit. Rev. Biotechnol., 37(6), 754 (2017)
  28. Xin X, Wei Q, Yang J, Yan L, Feng R, Chen G, Du B, Li H, Chem. Eng. J., 184, 132 (2012)
  29. Wang YG, Shi L, Gao L, Wei Q, Cui LM, Hu LH, Yan LG, Du B, J. Colloid Interface Sci., 451, 7 (2015)
  30. Raghubanshi H, Ngobeni SM, Osikoya AO, Shooto ND, Dikio CW, Naidoo EB, Dikio ED, Pandey RK, Prakash R, J. Ind. Eng. Chem., 47, 169 (2017)
  31. Guo XY, Du B, Wei Q, Yang J, Hu LH, Yan LG, Xu WY, J. Hazard. Mater., 278, 211 (2014)
  32. Cui LM, Wang YG, Gao L, Hu LH, Yan LG, Wei Q, Du B, Chem. Eng. J., 281, 1 (2015)
  33. Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA, Carbon, 47, 145 (2009)
  34. Schniepp HC, Li JL, McAllister MJ, Sai H, Herrera-Alonso M, Adamson DH, Prud'homme RK, Car R, Saville DA, Aksay IA, J. Phys. Chem. B, 110(17), 8535 (2006)
  35. Terracciano A, Zhang J, Christodoulatos C, Wu F, Meng X, J. Environ. Sci., 57, 8 (2017)
  36. Guo LQ, Ye PR, Wang J, Fu FF, Wu ZJ, J. Hazard. Mater., 298, 28 (2015)
  37. Weng CH, J. Colloid Interface Sci., 272(2), 262 (2004)
  38. Faria AF, Martinez DSFT, Moraes AC, da Costa MEM, Barros EB, Filho AGS, Paula AJ, Alves OL, Chem. Mater., 24(21), 4080 (2012)
  39. Thomas HR, Valles C, Young RJ, Kinloch IA, Wilson NR, Rourke JP, J. Mater. Chem. C, 1(2), 338 (2013)
  40. Bonanni A, Ambrosi A, Chua CK, Pumera M, ACS Nano, 8(5), 4197 (2014)
  41. Guo Z, Wang S, Wang G, Niu Z, Yang J, Wu W, Carbon, 76, 203 (2014)
  42. Luo T, Tian H, Guo Z, Zhuang G, Jing C, Environ. Sci. Technol., 47(19), 10939 (2013)