50 μm급 이트리아 안정화 지르코니아 비드의 미세구조 및 마모 조건에 따른 마모율 분석

김정환; 윤세중; 한병동; 안철우; 윤운하; 최종진; Jung-Hwan Kim; Sae-Jung Yoon; Byung-Dong Hahn; Cheol-Woo Ahn; Woon-Ha Yoon; Jong-Jin Choi

Korean Journal of Materials Research, Vol.29, No.4, 233-240, April, 2019

DOI10.3740/MRSK.2019.29.4.233 Export Citation

50 μm급 이트리아 안정화 지르코니아 비드의 미세구조 및 마모 조건에 따른 마모율 분석

Analysis of Attrition Rate of 50 μm Size Y2O3 Stabilized Zirconia Beads with Different Microstructure and Test Conditions

김정환¹, 윤세중^{1, 2}, 한병동^{1, 2}, 안철우¹, 윤운하¹, 최종진^{1, †}

¹한국기계연구원 부설 재료연구소 기능세라믹연구실
²과학기술연합대학원 대학교 신소재공학 전공

Jung-Hwan Kim¹, Sae-Jung Yoon^{1, 2}, Byung-Dong Hahn^{1, 2}, Cheol-Woo Ahn¹, Woon-Ha Yoon¹, and Jong-Jin Choi^{1, †}

¹Functional Ceramics Department, Korea Institute of Materials Science, Changwon 51508, Republic of Korea
²Advanced Materials Engineering, University of Science and Technology (UST), Daejeon 34113, Republic of Korea

E-mail:

This study analyzes the mechanical properties, including the attrition rate, of 50 μm size yttria-stabilized zirconia (YSZ) beads with different microstructures and high-energy milling conditions. The yttria distribution in the grain and grainboundary of the fully sintered beads relates closely to Vickers hardness and the attrition rate of the YSZ beads. Grain size, fractured surfaces, and yttrium distribution are analyzed by electronic microscopes. For standardization and a reliable comparison of the attrition rate of zirconia beads with different conditions, Zr content in milled ceramic powder is analyzed and calculated by X-ray Fluorescence Spectrometer(XRF) instead of directly measuring the weight change of milled YSZ beads. The beads with small grain sizes sintered at lower temperature exhibit a higher Vickers hardness and lower attrition rate. The attrition rate of 50 μm YSZ beads is measured and compared with the various materials properties of ceramic powders used for high-energy milling. The attrition rate of beads appears to be closely related to the Vickers hardness of ceramic materials used for milling, and demonstrates more than a 10 times higher attrition rate with Alumina(Hv ~1650) powder than BaTiO3 powder (Hv ~315).

Keywords:ceramic beads;attrition rate;YSZ;zirconia;TZP

[References]

Norhasri MS, Hammidah MS, Fadzil AM, Constr. Build. Mater., 133, 91 (2017)
Filipponi L, Surherland D, NANOTECHNOLOGIES, European Commission, Luxembourg, EU (2013).
Gleiter H, Prog. Mater. Sci., 33, 4 (1990)
Mishra RS, Valiev RZ, Mukherjee AK, Nanostruct. Mater., 9, 473 (1997)
Kwade A, Powder Technol., 105(1-3), 14 (1999)
Yadav TP, Yadav RM, Singh DP, Nanosci. Nanotechnol., 2, 22 (2012)
Zhang DL, Prog. Mater. Sci., 49(3-4), 537 (2004)
Shinohara K, Golman B, Uchiyama T, Otani M, Powder Technol., 103(3), 292 (1999)
Becker M, Schwedes J, Powder Technol., 105(1-3), 374 (1999)
Bamba N, Choa YH, Sekino T, Niihara K, J. European Ceram. Soc., 23, 773 (2003)
Trunec M, Ceramics- Silikaty, 52, 165 (2008).
Hannink RHJ, Kelly PM, Muddle BC, J. Am. Ceram. Soc., 83(3), 461 (2000)
Lange FF, J. Mater. Sci., 17, 225 (1982)
Stemmer S, Vleugels J, Biest OVD, J. European Ceram. Soc., 18, 1565 (1998)
Matsui K, Yoshida H, Ikuhara Y, Acta Mater., 56, 1315 (2008)
Nettleship I, Stevens R, Int. J. High Tech. Ceram., 3, 1 (1987)
Vasylkiv O, Sakka Y, Skorokhod VV, Mater. Trans., 44, 2235 (2003)
Hoepfner TP, Case ED, Ceram. Int., 29, 699 (2003)
ASM Handbook, “Volume 15 Casting.” Materials Park: ASM International (2008)
Totten, George E. “ASM Handbook, Volume 18: Friction, Lubrication, and Wear Technology.” (2017).
Shackelford JF, Han YH, Kim S, Kwon S, H.CRC materials science and engineering handbook. CRC press, (2016).

[1] Norhasri MS, Hammidah MS, Fadzil AM, Constr. Build. Mater., 133, 91 (2017)

[2] Filipponi L, Surherland D, NANOTECHNOLOGIES, European Commission, Luxembourg, EU (2013).

[3] Gleiter H, Prog. Mater. Sci., 33, 4 (1990)

[4] Mishra RS, Valiev RZ, Mukherjee AK, Nanostruct. Mater., 9, 473 (1997)

[5] Kwade A, Powder Technol., 105(1-3), 14 (1999)

[6] Yadav TP, Yadav RM, Singh DP, Nanosci. Nanotechnol., 2, 22 (2012)

[7] Zhang DL, Prog. Mater. Sci., 49(3-4), 537 (2004)

[8] Shinohara K, Golman B, Uchiyama T, Otani M, Powder Technol., 103(3), 292 (1999)

[9] Becker M, Schwedes J, Powder Technol., 105(1-3), 374 (1999)

[10] Bamba N, Choa YH, Sekino T, Niihara K, J. European Ceram. Soc., 23, 773 (2003)

[11] Trunec M, Ceramics- Silikaty, 52, 165 (2008).

[12] Hannink RHJ, Kelly PM, Muddle BC, J. Am. Ceram. Soc., 83(3), 461 (2000)

[13] Lange FF, J. Mater. Sci., 17, 225 (1982)

[14] Stemmer S, Vleugels J, Biest OVD, J. European Ceram. Soc., 18, 1565 (1998)

[15] Matsui K, Yoshida H, Ikuhara Y, Acta Mater., 56, 1315 (2008)

[16] Nettleship I, Stevens R, Int. J. High Tech. Ceram., 3, 1 (1987)

[17] Vasylkiv O, Sakka Y, Skorokhod VV, Mater. Trans., 44, 2235 (2003)

[18] Hoepfner TP, Case ED, Ceram. Int., 29, 699 (2003)

[19] ASM Handbook, “Volume 15 Casting.” Materials Park: ASM International (2008)

[20] Totten, George E. “ASM Handbook, Volume 18: Friction, Lubrication, and Wear Technology.” (2017).

[21] Shackelford JF, Han YH, Kim S, Kwon S, H.CRC materials science and engineering handbook. CRC press, (2016).