Enhanced Olefin and CO2 Permeance Through Mesopore-Confined Ionic Liquid Membrane

Il Seok Chae; Gil Hwan Hong; Donghoon Song; Yong Soo Kang; Sang Wook Kang

Macromolecular Research, Vol.27, No.3, 250-254, March, 2019

DOI10.1007/s13233-019-7036-1 Export Citation

Enhanced Olefin and CO2 Permeance Through Mesopore-Confined Ionic Liquid Membrane

Il Seok Chae¹, Gil Hwan Hong², Donghoon Song¹, Yong Soo Kang^{1, †}, and Sang Wook Kang^{2, 3, †}

¹Department of Energy Engineering, Hanyang University, Seoul 04763, Korea
²Department of Chemistry, Sangmyung University, Seoul 03016, Korea
³Department of Chemistry and Energy Engineering, Sangmyung University, Seoul 03016, Korea

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Nanocomposites of ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF4), in three-dimensional mesoporous silica (KIT-6) were fabricated and utilized as mesopore-confined ionic liquid membranes for Olefin and CO2 Separation. Compared to neat BmimBF4, the fabricated membrane showed 10-times-enhanced gas permeation property for olefin separation, and 5-times-enhanced gas permeation property for CO2 separation with gas-selectivity remaining unchanged. Moreover, the enhanced diffusion-limited current density of the electrochemical cell involving I-/I3- redox couple in BmimBF4/KIT-6 nanocomposite was observed. This implies that mesoporous KIT-6 can be used as an effective additive in nanocomposite membranes for enhanced olefin and CO2 permeance.

Keywords:mesoporous materials;ionic liquids;CO2;olefin separation;and iodine diffusion

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[15] Camper D, Scovazzo P, Koval C, Noble R, Ind. Eng. Chem. Res., 43(12), 3049 (2004)

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