The effect of Ce loading content on Ni-CeO2/Al2O3 catalysts for CO2 plasma methanation was evaluated. Catalysts were prepared by one-pot evaporation-induced self-assembly, Ni content was fixed at 15 wt. %, while CeO2 ranged 0-50 wt. %. The catalysts performances were tested under atmospheric pressure in two operation modes, thermal- and plasma-catalysis. As for conventional thermal catalysis, the catalyst was thermally activated between 200 and 400 degrees C; while in plasma-catalysis, the catalyst was activated by plasma generated by a dielectric barrier discharges (DBD) reactor. By the application of plasma in the catalyst bed, the reaction temperature was reduced from 350 degrees C to 150 degrees C to obtain the same level of conversion than thermal-catalysis. In addition, the incorporation of Ce in Ni-CeO2/Al2O3 led to an improvement of the catalytic performance in both thermal- and plasma-catalysis. Nevertheless, divergences on the optimum Ce content were found. On plasma experiments, the catalyst was more active at a lower amount of CeO2 ((similar to)10 wt.%) with respect to thermal catalysis ((similar to)40 wt.%), reducing the catalyst fabrication cost. Those differences highlights that the CO generated by plasma CO2 dissociation has a significant role for methane production, and thus the need to consider the by-products as reactant for the optimization of catalysts composition for DBD plasma-catalysis.