화학공학소재연구정보센터
Applied Surface Science, Vol.480, 851-860, 2019
Multifunctional magnetic superhydrophobic carbonaceous aerogel with micro/nano-scale hierarchical structures for environmental remediation and energy storage
Multifunctional magnetic superhydrophobic carbonaceous (MSC) aerogel with hierarchically porous structures is successfully prepared via carbonization process using disposable cotton balls followed by surface-coating of Fe3O4 particles and post hydrophobic-modified treatment with long-chain silanes. The developed MSC aerogel demonstrates ultralow density (< 2 mg/cm(3)) and ultrahigh porosity (> 99.9%), robust superhydrophobicity and superoleophilicity (theta(water) = 160.5 degrees, theta(oil) = 0 degrees, a rolling contact angle of 1.8 degrees). The aerogel has excellent absorption capacity (61-113 g/g) for various oily liquids, and can be manipulated above the contaminated water under magnetism. More importantly, benefitting from its fire resistance and compressibility, the MSC aerogel can be recycled easily using distillation, squeezing and combustion, depending on the kinds of contaminants. Furthermore, this material can be a good candidate for supercapacitors. All these features make the material a versatile and comprehensive material for various applications in oil spill cleanup and energy storage.