Catalysis Letters, Vol.149, No.5, 1224-1236, 2019
Bioinspired Palladium Nanoparticles Supported on Soil-Derived Humic Acid Coated Iron-Oxide Nanoparticles as Catalyst for C-C Cross-Coupling and Reduction Reactions
Pd nanoparticles supported on humic acid-coated nanoferrites as magnetically-recoverable catalyst was expediently prepared from inexpensive precursors and characterized by techniques such as SEM, TEM, XPS, FT-IR, XRD, ICP-AES, EDX. The as made catalyst displayed an admirable catalytic activity towards the Suzuki-Miyaura cross-coupling reaction of aryl halides (or) aryl diazonium salts with aryl boronic acid in non-toxic solvent EtOH/water under mild conditions. The same catalyst showed high efficiency for the Heck reaction of aryl halides with styrene was carried out with high efficiency offering good yields under ligand-free conditions. Additionally, the reduction of olefins using molecular hydrogen was also achieved using the same catalyst under ambient and base-free conditions affording the products in good to excellent yields. The magnetic activity of nano-Fe3O4 allowed the effortless recovery of the catalyst and demonstrated subsequent recyclability up to 5 cycles without a significant loss in the activity. [GRAPHICS] .