화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.44, No.22, 11280-11288, 2019
Hydrogen enriched syngas production via gasification of biofuels pellets/powders blended from olive mill solid wastes and pine sawdust under different water steam/nitrogen atmospheres
In this work, we study the gasification of pellets produced, after densification, by blending olive mill solid wastes, impregnated or not by olive mill waste water, and pine sawdust under different steam/nitrogen atmospheres. The charcoals necessary for the gasification tests were prepared by pyrolysis using a fixed bed reactor. The gasification technique using steam was chosen in order to produce a hydrogen-enriched syngas. Gasification tests were performed using macro-thermogravimetric equipment Tests were carried out at different temperatures (750 degrees C, 800 degrees C, 820 degrees C, 850 degrees C and 900 degrees C), and at different atmospheres composed by nitrogen and steam at different percentages (10%, 20% and 30%). Results show that the mass variation profiles is similar to the usual lingo-cellulosic gasification process. Moreover, the increase of temperatures or water steam partial pressures affects positively the rate of conversion and the char reactivity by accelerating the gasification process. The increase of the gasification yields demonstrates the promise of using olive mill by-products as alternative biofuels (H-2 enriched syngas). (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.