With the aid of computer simulation, we have designed four covalent-organic frameworks based on tetrakis(4-aminophenyl)silsesquioxane (taps-COFs) and their hydrogen storage properties were predicted with grand canonical Monte Carlo (GCMC) simulation. The structural parameters and physical properties were investigated after the geometrical optimization. The accessible surface for H-2 molecule (5564.68-6754.78 m(2)/g) were estimated using the numerical Monte Carlo integration and the pore volume (4.06-10.74 cm(3)/g) was evaluated by the amounts of the containable nonadsorbing helium molecules at low pressures and room temperature. GCMC simulation reveals that at 77 K, taps-COF-1 has the highest gravimetric H-2 adsorption capacity of 51.43 wt% and taps-COF-3 possesses the highest volumetric H-2 adsorption capacity of 58.51 g/L. Excitedly, at room temperature of 298 K, the gravimetric hydrogen adsorption capacities of taps-COF-1 (8.58 wt%) and taps-COF-2 (8.20 wt%) have exceeded the target (5.5 wt%) of onboard hydrogen storage system for 2025 set by the U.S Department of Energy. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.