화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.44, No.16, 8627-8640, 2019
An investigation of the effect of hydrogen on ductile fracture using a unit cell model
The effect of hydrogen on the ductility of metals is studied by incorporating the hydrogen diffusion process and the hydrogen enhanced localized plasticity (HELP) into a finite element program. A series of unit cell analyses are conducted under various stress states and the loading speed resulting in a steady state hydrogen distribution is determined. The evolution of the local stress and deformation states results in hydrogen redistribution in the material, which in turn changes the material's flow property due to the HELP effect. It is found that localized plastic deformation plays a major role in increasing the hydrogen concentration due to the newly generated trapping sites. The HELP effect promotes material failure by accelerating void growth, which is affected by the macroscopic stress state subjected by the material unit characterized by the stress triaxiality and the Lode parameter. For a constant Lode parameter, the effect of HELP on void growth and failure strain reduction increases with the stress triaxiality. For a constant stress triaxiality, the effect of HELP is highest when the Lode parameter is near 0. As the Lode parameter increases towards 1 or decreases towards -1, the HELP effect gradually diminishes. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.