This work explores high-speed impact of fully age-hardened 15-5 PH stainless steel with itself at average impact speed of 682m/s and impact angles ranging from 8 degrees to 28 degrees. It was assumed that higher angles corresponded with higher shear stresses at impact point. Microstructural examination indicated more pronounced shear-induced features at higher angles, such as nanoscale elongated grains and adiabatic shear bands. Interfacial waves, a feature associated with impact welding, were most prominent at 12 degrees and 16 degrees. White etching layers (WELs), a constituent formed by rapid heating and cooling at impact, were found along the impact interface and most prominently at the front and back vortices of the interfacial waves. WELs (along the interface) were softer than base materials due to overaging, whereas materials surrounding the interface were harder than base materials due to grain refinement. Numerical simulations based on smoothed particle hydrodynamics method were employed to predict the local temperature and strain distributions which supported microstructural findings. Thus, through high-speed impact experiments carried out at different angles along with advanced microscopy and numerical simulations, this work helped reveal the microstructural response of 15-5 PH stainless steel in a range of dynamic shear conditions.