Materials Chemistry and Physics, Vol.225, 256-260, 2019
Controlling xi-Ta4C3-x laminate growth in TaC0.6 ceramic by addition of Cu and its effect on mechanical properties
Tantalum carbide ceramics with an overall composition of TaC0.6 were prepared by hot pressing at 1700 degrees C for 1 h under 30 MPa pressure with fcc TaC and bcc Ta powder as starting materials. Effects of adding 0-30 mol% Cu on densification, phase formation, microstructural evolution, mechanical properties and electrical conductivity of the obtained composite ceramics were investigated. Full density could be reached at 20 mol% Cu addition and above. Reactions between TaC and Ta resulted in the final phases of hexagonal Ta2C and rhombohedral xi-Ta4C3-x. Plate-shaped xi laminate grew in both TaC and Ta2C and consequently had their sizes confined by the parental grains. Addition of 20-30 mol% Cu could significantly grow the intermediate Ta2C grains, hence controlling length of the laminates precipitated in them to form bimodal microstructures consisting of large grains. The 20 mol% Cu composition had a better flexural strength (706 +/- 46 MPa) and fracture toughness (9.2 +/- 1.7 MPa m(1/2)). Electrical resistivity at room temperature of the composites decreased with Cu content from 1.03 mu Omega m at 0 mold/0 addition to 0.12 mu Omega m at 30 mol% Cu.