Manufacturing of flexible electrochromic (EC) devices requires the use of low-temperature films for deposition on electronically conductive foils. With this aim, low-temperature V-oxide films were spin-coated from a dispersion prepared by milling of crystalline V2O5 powder in vanadium(V) tri-n-propoxide oxide/isopropanol sol as dispersant. TEM images showed that the milling procedure enables the introduction of some V2O5 nanocrystallites into the matrix of the V-oxide pigmented film prepared at 150 degrees C. The electrochromic properties were analyzed using in situ UV-visible absorbance spectroelectrochemistry. The low transmittance values of as-prepared pigmented films revealed the presence of a greater amount of reduced V4+ centers compared to the crystalline sol-gel V2O5 model films. Significant bleaching of pigmented V-oxide films occurred during subsequent 521 cycles in the safe potential range. Three different types of vibrational spectroscopies were applied to examine the powdered V-oxide film, and the results were compared to the band changes for the sol-gel crystalline V2O5 films. For initial films, the modes in the IR reflection-absorption spectra were systematically shifted to higher wavenumbers with regard to the modes in the IR absorbance spectra. Both IR techniques confirmed the reversible shift of the vanadyl V-O-A band to lower frequencies and the disappearance of the bridging V-O-B-V mode upon intercalation. Raman spectra showed the appearance of two vanadyl stretching modes at 986 and 961 cm(-1) that occurred simultaneously with the decrease in the intensity of the bands in the 750-400 cm(-1) spectral region. After the deintercalation, the Raman spectra of the low-temperature films showed broad bands that remained after the second bleaching. Finally, a flexible NiO1-x/ormolyte/V-oxide EC device was constructed. The device was composed of two different pigmented films and demonstrated the practical applicability of the low-temperature pigmented films.