Journal of Industrial and Engineering Chemistry, Vol.75, 108-114, July, 2019
Effect of nano-pinholes within ceramic electrolytes of thin-film solid oxide fuel cells
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The effect of nano-pinholes in the ceramic electrolyte (yttria-stabilized zirconia) on the performance of a thin-film solidoxide fuel cell(SOFC) is investigated.As a result, the open-circuitvoltage of the thin-film SOFC was not severely affected by the existence and the size of a pinhole. However, the pinhole induced a critical electrical shortage between the anode and cathode if the cathode was deposited onto the pinhole. Thus, a nano-sized pinholedoes not significantly induce fuel crossoverorcritically reduce the performance. It could, however, reduce the performance significantly during the common fabrication step, i.e. deposition of thin- film cathode on an electrolyte, of a thin-film SOFC, especially for larger pinholes.
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