The kinetic parameters for chemical reactions associated with the vaporization of arsenic species are rarely reported due to the difficulties in obtaining suitably purified arsenic compounds as well as the issues associated with the extreme toxicity of many arsenic species. Here, we used a single-particle coal combustion model combined with a vaporization yield model of arsenic fitted by experimental data, which was used to determine the activation energy and frequency factor of the oxidation/decomposition reactions of arsenic species in this work, namely: As-org, FeAsS, FeAsO4 and Ca-3(AsO4)(2). The combustion kinetics of volatile/char and arsenic thermodynamic properties were used to model the vaporization zone and intensity of emissions for arsenic compounds. The results show that the reaction kinetic parameters of these arsenic species could be determined within an order of magnitude despite the variation of compositions in the coal sample and temperature, and this approach provides a new method to determine the reaction kinetics of hazardous elements such as As. Combining the vaporization yield and reaction kinetics of arsenic species with the single-particle coal combustion model, a novel vaporization model of arsenic was developed. With this model, the temporal evolution of combustion parameters (temperature, conversion ratio of coal, particle porosity, flue gas concentration) as well as arsenic vaporization ratio and As2O3(g) concentration can be predicted at the microscopic level. (C) 2019 The Combustion Institute. Published by Elsevier Inc. All rights reserved.