In this study, highly pure hydrogen is produced in sorption enhanced chemical looping steam methane reforming (SE-CLSMR) using cobalt-based oxygen carrier (OC) and cerium promoted CaO-based sorbent. In addition, the CO2 removal from a gas stream at high temperatures is investigated via calcium looping process prior to SE-CLSMR process. The prepared samples are characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and energy dispersive X-ray spectroscopy (EDX) techniques. The effect of Ca/Ce molar ratio (100/0.00-0.91/0.09), sorption temperature (550-650 degrees C) and sorbent lifetime are studied to find the optimal sorbent. The characterization results show the uniform and orderly CeO2 dispersed sorbent nanoparticles that notably improved the sorbent morphology compared with blank CaO. The sorption results revealed the negative effect of temperature on CO2 uptake of all the samples. In addition, the CO2 sorption evaluations indicate that the molar ratio of cerium to calcium plays a significant role in the stability of sorbent and improved the CO2 sorption capacity significantly. The high CO2 removal efficiency in the cerium modified sorbents could be due to decrease in diffusion resistance of CO2 through the sorbent structure during the carbonation reaction. Furthermore, results show that the addition of cerium to the sorbent structure, effectively improves the thermal resistance of synthesis sorbents. The SE-CLSMR results showed that the H-2 purity could be increased up to about 95% considering Co3O4/SiO2 oxygen carrier and cerium promoted calcium-based sorbent at relatively low temperature of 550 degrees C, which is comparable with 84% in CLR process. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.