Syngas production via dry reforming of methane (DRM) was experimentally investigated using Ni-based catalyst. Ni/Al2O3 modification with CeO2 addition and O-2 addition in the reactant were employed in this study to suppress carbon deposition and to enhance catalyst activity. It was found that DRM performance can be enhanced using CeO2 modified Ni/Al2O3 catalyst due to CeAlO3 formation. However, an optimum amount of CeO2 loading exists to obtain the best DRM performance due to the decrease in specific surface area as the CeO2 loading increases. Without O-2 addition, the reverse water-gas shift reaction plays an important role in DRM. It was found that CH4 conversion and CO yield were enhanced while CO2 conversion and H-2 yield are decreased as the CO2 amount in feedstock increased in DRM. With O-2 addition in the fed reactant, it was found that the methane oxidation reaction plays an important role in DRM. CH4 conversion can be enhanced by O-2 addition. However, decreases in CO2 conversion and H-2 and CO yields occurred due to greater H2O and CO2 productions from the methane oxidation reaction. The thermogravimetric analysis (TGA) results showed that CeO2 modified Ni/Al2O3 catalyst would have the lowest amount of carbon deposition when O-2 is introduced into the reaction. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.