화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.166, No.12, D487-D495, 2019
Accelerated Bottom-Up Gold Filling of Metallized Trenches
This work extends previously detailed void-free, bottom-up feature filling in a near-neutral Na3Au(SO3)(2) + Na2SO3 electrolyte containing micromolar concentrations of Bi3+. Bottom-up electrodeposition in 17 mu m and 45 mu m tall trenches with an aspect ratio greater than 10 is demonstrated using potentiostatic, stepped potential and/or stepped current control. Strategies to shorten the incubation period associated with slow deposition on uniformly passivated surfaces, which precedes bottom-up filling at fixed potential, are explored. The first electron backscatter diffraction studies of bottom-up filled Au deposits reveal large grains that span the trench width and often exceed tens of micrometers in length. In contrast, smaller grains are observed near the tops of filled trenches and, under conditions of marginal filling, mid-height within them. (C) 2019 The Electrochemical Society.