화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.36, No.9, 1432-1440, September, 2019
DOI10.1007/s11814-019-0336-5  Export Citation
CO2 capture and preparation of spindle-like CaCO3 crystals for papermaking using calcium carbide residue waste via an atomizing approach
Liang Ma1, 2, Tingyu Yang2, 3, Yu Wu2, 3, Xiaoqing Yue2, 3, Jinrong Yang2, 3, Shuai Zhang2, 3, Qiang Li2, 3, and Jianbin Zhang1, 2, †
  • 1Key Laboratory of Coal-based CO2 Capture and Geological Storage, China University of Mining and Technology, Xuzhou, 221008, China
  • 2College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
  • 3Inner Mongolia Engineering Research Center for CO2 Capture and Utilization, Hohhot 010051, China, China
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Spindle-like CaCO3 crystals with controllable sizes for papermaking were successfully prepared using CO2 (8% CO2/N2 mixture gas) and calcium carbide residue (CCR) waste, a by-product of acetylene gas and polyvinyl chloride production, as the raw materials by an atomization method at room temperature. The influences of solution concentration, reaction temperature, and gas/liquid flow rate ratios on the properties of the CaCO3 crystal were systematically investigated, and a possible atomization mechanism was proposed. The size of the as-prepared CaCO3 crystal with pure calcite phase was turned from 4.71×4.02 μm to 1.82×1.12 μm by adjusting the reaction conditions. The application of the as-prepared CaCO3 crystals from CCR waste as a filler for papermaking was explored. The R475 blue light whiteness of paper was increased from 77.3 to 80.6 with 11.4% CaCO3 crystals.
Keywords:Calcium Carbide Residue (CCR);Spindle-like CaCO3;Carbon Dioxide Capture;Atomization;Papermaking
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