화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.79, 131-145, November, 2019
DOI10.1016/j.jiec.2019.06.017  Export Citation
Thermodynamic and kinetic effect of biodegradable polymers on carbondioxide hydrates
Sana Yaqub1, 2, Bhajan lal1, 2, †, and Lau Kok Keong1, 2
  • 1Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar 32610, Perak, Malaysia
  • 2CO2 Research Centre (CO2RES), Universiti Teknologi PETRONAS, Bandar Seri Iskandar 32610, Perak, Malaysia
E-mail:
In this work, the effect of biodegradable polymers, i.e. pectin (PC), sodium-carboxymethyl cellulose (Na- CMC), tapioca starch (TS) and dextran (DX) on thermodynamics and kinetics of CO2 hydrates are evaluated on sapphire hydrate reactor. The CO2 hydrate liquid vapour equilibrium (HLwVE) data is evaluated in the presence of biopolymers (1.5 wt%) using isochoric T-cycle method at temperature and pressure ranging from 278.7 to 283.0 K and 2.3 to 4.3 MPa respectively. The effect of biopolymers on HLwVE curve is reported by measuring average increment temperature (ΔT). The constant cooling method is used to evaluate the kinetics of CO2 hydrates at 4.3 MPa in the presence of biopolymers (0.12. 1.5 wt%) at 274.15 K and 277.15 K. The inhibition effect of biopolymers on the kinetics of CO2 hydrate is reported by measuring induction time, hydrate formation rate and amount of gas consumed. The kinetic inhibition strength of biopolymers is compared with poly-N-vinylpyrrolidone (PVP) and with two noncommercial inhibitors, i.e. glycine and tetra-methyl ammonium chloride (TMACl) through relative inhibition strength (RIS). Results reveal that DX shows maximum increment temperature of 0.36 K. While PC and Na-CMC delayed CO2 hydrate nucleation for 423 and 181 min respectively. Additionally, biodegradation study on biopolymers indicates that, compared to PVP, biopolymers are easily biodegradable and show potential for gas hydrate offshore applications.
Keywords:Thermodynamic CO2 hydrate promoters;Kinetic CO2 hydrate inhibitors;Biopolymers;Biodegradability;Flow assurance
  1. Sloan ED, Koh C, Clathrate Hydrates of Natural Gases, CRC Press, 2007.
  2. Xiao CW, Wibisono N, Adidharma H, Chem. Eng. Sci., 65(10), 3080 (2010)
  3. Sloan ED, Koh CA, Clathrate Hydrates of Natural Gases, third edition, CRC Press, pp.119 2008.
  4. Foo KS, Khan MS, Lal B, Sufian S, IOP Conf. Ser. Mater. Sci. Eng., 458, 12060 (2018)
  5. Roosta H, Dashti A, Mazloumi SH, Varaminian F, J. Mol. Liq., 215, 656 (2016)
  6. Kelland MA, Svartaas TM, Dybvik L, Studies on New Gas Hydrate Inhibitors, Offshore Eur., Society of Petroleum Engineers, 1995.
  7. Chen J, Yan KL, Chen GJ, Sun CY, Liu B, Ren N, Shen DJ, Niu M, Lv YN, Li N, Sum AK, Chem. Eng. Sci., 122, 284 (2015)
  8. Arjmandi M, Tohidi B, Danesh A, Todd AC, Chem. Eng. Sci., 60(5), 1313 (2005)
  9. Kelland MA, Svartaas TM, Ovsthus J, Tomita T, Mizuta K, Chem. Eng. Sci., 61(13), 4290 (2006)
  10. Karig SP, Shin JY, Lim JS, Lee S, Chem. Eng. Sci., 116, 817 (2014)
  11. Kelland MA, Energy Fuels, 20(3), 825 (2006)
  12. Perrin A, Musa OM, Steed JW, Chem. Soc. Rev., 42, 1996 (2013)
  13. Sloan ED, Natural Gas Hydrates in Flow Assurance, Gulf Professional Publishing, 2010.
  14. Perrin A, Musa OM, Steed JW, Chem. Soc. Rev., 42, 1996 (2013)
  15. Liu WG, Wang SR, Yang MJ, Song YC, Wang SL, Zhao JF, J. Nat. Gas Sci. Eng., 24, 357 (2015)
  16. Zeng GM, Zhang LH, Dong HR, Chen YN, Zhang JC, Zhu Y, Yuan YJ, Xie YK, Fang W, Bioresour. Technol., 253, 112 (2018)
  17. Ross GM, Chem. Geol., 161, 5 (1999)
  18. Zhang LH, Zhang JC, Zeng GM, Dong HR, Chen YN, Huang C, Zhu Y, Xu R, Cheng YJ, Hou KJ, Cao WC, Fang W, Bioresour. Technol., 261, 10 (2018)
  19. Xu YJ, Yang ML, Yang XX, J. Nat. Gas Chem., 19, 431 (2010)
  20. Lu DR, Xiao CM, Xu SJ, Express Polym. Lett., 3, 366 (2009)
  21. Lee JD, Wu HJ, Englezos P, Chem. Eng. Sci., 62(23), 6548 (2007)
  22. Talaghat MR, J. Nat. Gas Sci. Eng., 18, 7 (2014)
  23. Talaghat MR, Can. J. Chem. Eng., 90(2), 429 (2012)
  24. Sa JH, Kwak GH, Lee BR, Park DH, Han K, Lee KH, Sci. Rep., 3, 2428 (2013)
  25. Bavoh CB, Nashed O, Khan MS, Partoon B, Lal B, Sharif AM, J. Chem. Thermodyn., 117, 48 (2018)
  26. Veluswamy HP, Lee PY, Premasinghe K, Linga P, Ind. Eng. Chem. Res., 56(21), 6145 (2017)
  27. Naeiji P, Arjomandi A, Varaminian F, J. Nat. Gas Sci. Eng., 21, 64 (2014)
  28. Bavoh CB, Partoon B, Lal B, Gonfa G, Khor SF, Sharif AM, Chem. Eng. Sci., 171, 331 (2017)
  29. Rad SA, Khodaverdiloo KR, Karamoddin M, Varaminian F, Peyvandi K, J. Nat. Gas Sci. Eng., 26, 819 (2015)
  30. Ohno H, Susilo R, Gordienko R, Ripmeester J, Walker VK, Chem. Eur. J., 16, 10409 (2010)
  31. Walker VK, Zeng H, Ohno H, Daraboina N, Sharifi H, Bagherzadeh SA, et al., Can. J. Chem., 93, 839 (2015)
  32. Zeng H, Wilson LD, Walker VK, Ripmeester JA, J. Am. Chem. Soc., 128(9), 2844 (2006)
  33. Gordienko R, Ohno H, Singh VK, Jia Z, Ripmeester JA, Walker VK, PLoS One, 5, e8953 (2010)
  34. Srungavarapu M, Patidar KK, Pathak AK, Mandal A, Appl. Clay Sci., 152, 211 (2018)
  35. Kelland MA, Monig K, Iversen JE, Lekvam K, Energy Fuels, 22(4), 2405 (2008)
  36. Al-Adel S, Dick JAG, El-Ghafari R, Servio P, Fluid Phase Equilib., 267(1), 92 (2008)
  37. Xiaolan L, Zuohui L, Yong Z, Rongqiang L, 7th Int. Conf. Gas Hydrates, (2011).
  38. Gupta P, Nair VC, Sangwai JS, J. Chem. Eng. Data (2019).
  39. Khan MS, Lal B, Keong LK, Ahmed I, Fuel, 236, 251 (2019)
  40. Khan MS, Lal B, Shariff AM, Mukhtar H, J. Mol. Liq., 274, 33 (2019)
  41. Del Villano L, Kelland MA, Chem. Eng. Sci., 65(19), 5366 (2010)
  42. Kelland MA, Energy Fuels, 32(12), 12001 (2018)
  43. Naeiji P, Arjomandi A, Varaminian F, J. Nat. Gas Sci. Eng., 21, 915 (2014)
  44. Lee JD, Wu HJ, Englezos P, Chem. Eng. Sci., 62(23), 6548 (2007)
  45. Xu SR, Fan SS, Fang ST, Lang XM, Wang YH, J. Chen, Sci. Rep., 6, 23220 (2016)
  46. Yaqub S, Shariff ABM, Mellon NB, J. Nat. Gas Sci. Eng. (2019).
  47. Yaqub S, Lal B, Mellon NB, Sufian SB, IOP Conf. Ser. Mater. Sci. Eng., 458 (2018)
  48. Bavoh CB, Lal B, Keong LK, Jasamai MB, Idress MB, Proc. Eng., 148, 1232 (2016)
  49. Bavoh CB , Partoon B, Keong LK, Lal B, Wilfred CD, Aljanadi Y, et al., Int. J. Appl. Chem., 12, 6 (2016)
  50. Partoon B, Malik SNA, Azemi MH, Sabil KM, Asia-Pacific J. Chem. Eng., 8, 916 (2013)
  51. Koh CA, Westacott RE, Zhang W, Hirachand K, Creek JL, Soper AK, Fluid Phase Equilib., 194, 143 (2002)
  52. Xu SR, Fan SS, Fang ST, Wang YH, Lang XM, Fuel, 206, 19 (2017)
  53. Preininger C, Klimant I, Wolfbeis OS, Anal. Chem., 66, 1841 (1994)
  54. Drolc A, Cotman M, Ros M, Accredit. Qual. Assur., 8, 138 (2003)
  55. Riehl M, J. Chem. Educ., 89, 807 (2012)
  56. Hach C, Water Analysis Handbook, Loveland, Color USA, pp.61 2002.
  57. Klein RL, Gibbs CR, J. Water Pollut. Control Fed., 2257 (1979).
  58. Arslan-Alaton I, Balcioglu IA, Arch. Environ. Contam. Toxicol., 43, 425 (2002)
  59. Khan MS, Bavoh CB, Partoon B, Lal B, Bustam MA, Shariff AM, J. Mol. Liq., 238, 533 (2017)
  60. Giavarini C, Maccioni F, Politi M, Santarelli ML, Energy Fuels, 21(6), 3284 (2007)
  61. Kimuro H, Yamaguchi F, Ohtsubo K, Kusayanagi T, Morishita M, Energy Conv. Manag., 34, 1089 (1993)
  62. Iijima M, Nakamura K, Hatakeyama T, Hatakeyama H, Carbohydr. Polym., 41, 101 (2000)
  63. Kvamme B, Kuznetsova T, Aasoldsen K, J. Mol. Graph. Model., 23, 524 (2005)
  64. Kocherbitov V, Carbohydr. Polym., 150, 353 (2016)
  65. O’Reilly R, Ieong NS, Chua PC, Kelland MA, Chem. Eng. Sci., 66, 6555 (2011)
  66. Yagasaki T, Matsumoto M, Tanaka H, J. Am. Chem. Soc., 137(37), 12079 (2015)
  67. Kelland MA, Svartaas TM, Øvsthus J, Namba T, Ann. N. Y. Acad. Sci., 912, 281 (2000)
  68. Qin HB, Sun CY, Sun ZF, Liu B, Chen GJ, Chem. Eng. Sci., 148, 182 (2016)
  69. Seo SD, Paik HJ, Lim DH, Lee JD, Energy Fuels, 31(6), 6358 (2017)
  70. Park S, Kim J, Choi I, Chang D, Seo Y, Shin J, et al., IPTC 2013 Int. Pet. Technol. Conf., (2013).
  71. Daraboina N, Linga P, Chem. Eng. Sci., 93, 387 (2013)
  72. Idris A, Mamun AA, Amin M, Soom M, Noor W, Azmin W, Pollut. Res., 22, 145 (2003)
  73. Gandaseca S, Rosli N, Ngayop J, Arianto CI, Am. J. Environ. Sci., 7, 269 (2011)
  74. Noraini R, Seca G, Johan I, Mohd IJ, Am. J. Environ. Sci., 6, 416 (2010)
  75. Khalik W, Abdullah MP, Amerudin NA, Padli N, J. Mater. Environ. Sci., 4, 488 (2013)
  76. Astel A, Bizuk M, Przyjazny A, Namiesnik J, Water Res., 40, 1706 (2006)
  77. Al-Badaii F, Shuhaimi-Othman M, Gasim MB, J. Chem., 2013 (2013).
  78. Harun S, Abdullah MH, Mohamed M, Fikri AH, Jimmy EO, J. Trop. Biol. Conserv., 1 (2010).