화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.9, 867-875, September, 2019
DOI10.1007/s13233-019-7126-0  Export Citation
A Ternary PEDOT-TiO2-Reduced Graphene Oxide Nanocomposite for Supercapacitor Applications
Deniz Gulercan1, Daniel Commandeur2, Qiao Chen2, and A. Sezai Sarac1, 3, †
  • 1Polymer Science and Technology, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey
  • 2Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, United Kingdom, UK
  • 3Nanoscience and Nanoengineering, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey
E-mail:
A ternary composite of poly(3,4-ethylene dioxythiophene) (PEDOT) was prepared using TiO2 through an emulsion polymerization method adjusting various weight ratios of TiO2 to PEDOT, and blending synthesized reduced graphene oxide (rGO) with this composite. The Fourier transform infrared spectrophotometry, ultraviolet-visible spectrophotometry, and X-ray diffraction analysis displayed characteristic features of PEDOT and TiO2. The morphology of the nano-hybrid structure was additionally investigated by scanning electron microscopy analysis. Pore size and surface area analysis of particles were characterized by the Brunauer-Emmett-Teller method. The electrochemical analysis showed that the specific capacitance (Csp) for PEDOT-TiO2-15-rGO was 18.9 F g-1 at 0.1 mA cm-2 current density.
Keywords:PEDOT;TiO2;electrochemistry;emulsion polymerization;spectroscopy
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