Novel Hierarchically Porous Melamine-Vanillin Polymer: Synthesis and Application for the Pb(II) Ion Removal in Wastewater

Hong-Gyu Seong; Jihyeong Ryu; Yingjie Qian; Jae Il So; Sung-Hyeon Baeck; Sang Eun Shim

Macromolecular Research, Vol.27, No.9, 882-887, September, 2019

DOI10.1007/s13233-019-7121-5 Export Citation

Novel Hierarchically Porous Melamine-Vanillin Polymer: Synthesis and Application for the Pb(II) Ion Removal in Wastewater

Hong-Gyu Seong, Jihyeong Ryu, Yingjie Qian, Jae Il So, Sung-Hyeon Baeck , and Sang Eun Shim^†

Department of Chemistry & Chemical Engineering, Inha University, 100 Inha-ro, Nam-gu, Incheon 22212, Korea

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Water pollution due to heavy metal ions from factories causes serious threats as the heavy metal ions are inclined to accumulate in living systems threat ening their health. Adsorption is considered one of the most promising wastewater purification techniques for its simple operation and high effectiveness compared with other techniques. Accordingly, a novel cost-effective and environmentally benign porous melamine-vanillin polymer (MVP) was synthesized via Schiff-base formation reaction, which was utilized for the removal of Pb(II) ions. The MVP achieved a high surface area of 745 m2 g-1 with a hierarchically porous structure consisting of 1 nm and 3-50 nm pores. Effects of the contact time and the initial heavy metal concentration on the adsorption of Pb(II) were studied. Due to the copious functional groups and the hierarchical pore size distribution, MVP was found to exhibit a good adsorption performance toward Pb(II) ions. The adsorption process was well-fitted to the Langmuir adsorption isotherm and the pseudo-1st-order kinetic model.

Keywords:porous organic polymer;vanillin;hierarchically porous structure;lead ion;adsorption

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[2] Schwarzenbach RP, Escher BI, Fenner K, Hofstetter TB, Johnson CA, Gunten UV, Wehrli B, Science, 313, 1072 (2006)

[3] Tan MX, Sun YN, Ying JY, Zhang Y, Energy Environ. Sci., 6, 3254 (2013)

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[10] Peric J, Trgo M, Medvidovic NV, Water Res., 38, 1893 (2004)

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[12] Yang GD, Tang L, Zeng GM, Cai Y, Tang J, Pang Y, Zhou YY, Liu YY, Wang JJ, Zhang S, Xiong WP, Chem. Eng. J., 259, 854 (2015)

[13] Gu J, Yuan S, Shu W, Jiang W, Tang S, Liang B, Pehkonen SO, Colloids Surf. A: Physicochem. Eng. Asp., 498, 218 (2016)

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