Graft Polymer를 이용한 수계 세라믹 잉크의 합성 및 프린팅 특성평가

이지현; 황해진; 김진호; 황광택; 한규성; Ji-Hyeon Lee; Hae-Jin Hwang; Jin-Ho Kim; Kwang-Taek Hwang; Kyu-Sung Han

Korean Journal of Materials Research, Vol.29, No.10, 639-646, October, 2019

DOI10.3740/MRSK.2019.29.10.639 Export Citation

Graft Polymer를 이용한 수계 세라믹 잉크의 합성 및 프린팅 특성평가

Synthesis and Printability of Aqueous Ceramic Ink with Graft Polymer

이지현^{1, 2}, 황해진², 김진호¹, 황광택¹, 한규성^{1, †}

¹한국세라믹기술원 도자융합기술센터
²인하대학교 신소재공학과

Ji-Hyeon Lee^{1, 2}, Hae-Jin Hwang², Jin-Ho Kim¹, Kwang-Taek Hwang¹, and Kyu-Sung Han^{1, †}

¹Ceramicware Technology Center, Korea Institute of Ceramic Engineering and Technology, Icheon 17303, Republic of Korea
²Division of Material Science and Engineering, Inha University, Incheon 22212, Republic of Korea

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Ink-jet printing is a manufacturing process technology that directly prints a digitalized design pattern onto a substrate using a fine ink jetting system. In this study, environmentally friendly yellow aqueous ceramic ink is synthesized by mixture of distilled water, yellow ceramic pigment and additives for ink-jet printing. The graft polymer, which combines electrostatic repulsion and steric hindrance mechanism, is used as a surfactant for dispersion stability of aqueous ceramic ink. Synthesized ceramic ink with graft polymer surfactant shows better dispersion stability than did ceramic ink with PAA surfactant; synthesized ink also shows desirable ink-jet printability with the formation of a single ink droplet during printability test. Finally, ceramic ink printed on glass substrate and ceramic ink with graft polymer surfactant shows a high contact angle without surface treatment on glass substrate. Consequently, it is confirmed that the ceramic ink with graft polymer surfactant can achieve high printing resolution without additional surface treatment process.

Keywords:ceramic ink;contact angle;ink-jet printing;printability

[References]

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[2] Jeong KM, Won JM, Lee YK, Koseki K, J. Korea TAPPI, 46, 46 (2014)

[3] Watanabe O, Hibino T, Sakakibara M, Qualicer 2012 XII Global Forum on Ceramic Tile, 73, 73 (2012).

[4] Creagh L, McDonald M, Letendre W, Equipment for Electronic Products Manufacturing, 8, 9 (2004).

[5] Kim CS, Park SJ, Sim W, Kim YJ, Yoo Y, Comput. Fluids, 38, 602 (2009)

[6] Yoshioka Y, Calvert PD, Jabbour GE, Macromol. Rapid Commun., 26(4), 238 (2005)

[7] He M, Stoevesandt O, Palmer EA, Khan F, Ericsson O, Taussig MJ, Nat. Methods, 5, 175 (2008)

[8] Delaney JT, Smith PJ, Schubert US, Soft Matter, 5, 4866 (2009)

[9] Ilkhanizadeh S, Teixeira AI, Hermanson O, Biomaterials, 28, 3936 (2007)

[10] Kobayashi H, Matsuoka M, Nagae M, Honda H, Suzuki T, Ogawa K, Maeda H, Soc. Imaging Sci. Technol., 2, 903 (2008)

[11] Singlard M, Aimable A, Lejeune M, Dossou-Yovo C, Poncelet M, Noguera R, Modes C, Powder Technol., 266, 303 (2014)

[12] Gungor GL, Kara A, Gardini D, Blosi M, Dondi M, Zanelli C, Dyes Pigment., 127, 148 (2016)

[13] Clark EA, Alexander MR, Irvine DJ, Roberts CJ, Wallace MJ, Sharpe S, Yoo J, Hague RJM, Tuck CJ, Wildman RD, Int. J. Pharm., 529, 523 (2017)

[14] Saleh E, Woolliams P, Clarke B, Gregory A, Greedy S, Smartt C, Wildman R, Ashcroft I, Hague R, Dickens P, Tuck C, Addit. Manuf., 13, 143 (2017)

[15] Pan Z, Wang Y, Huang H, Ling Z, Dai Y, Ke S, Ceram. Int., 41, 12515 (2015)

[16] Ferrari G, Zannini P, Bol. Soc. Esp. Ceram. vidr., 56, 226 (2017)

[17] Morrison NF, Harlen OG, Rheol. Acta, 49(6), 619 (2010)

[18] Reis N, Ainsley C, Derby B, J. Appl. Phys., 97, 094903 (2005)

[19] Friederich A, Binder JR, Bauer W, J. Am. Ceram. Soc., 96, 2093 (2013)

[20] Whitby CP, Scales PJ, Grieser F, Healy TW, Kirby G, Lewis JA, Zukoski CF, J. Colloid Interface Sci., 262(1), 274 (2003)

[21] Kuscer D, Stavber G, Trefalt G, Kosec M, J. Am. Ceram. Soc., 95(2), 487 (2012)

[22] Hoefdraad HE, J. Inor. Nucl. Chem., 37, 1917 (1975)

[23] Pawlak D, Frukacz Z, Mierczyk Z, Suchocki Z, Zachara J, J. Alloy. Compd., 275, 361 (1998)

[24] De G, Licciulli A, Nacucchi M, J. Non-Cryst. Solids, 201, 153 (1996)

[25] Lemarchand C, Couvreur P, Vauthier C, Costantini D, Gref R, Int. J. Pharm., 254, 77 (2003)

[26] Mengual O, Meunier G, Cayre I, Puech K, Snabre P, Talanta, 50, 445 (1999)

[27] Lee JH, Hwang HJ, Kim JH, Hwang KT, Han KS, J. Kor. Ceram Soc., 53, 75 (2016)

[28] Solana VS, Qualicer, 14, 1 (2014)

[29] Stringer J, Derby B, J. Eur. Ceram. Soc., 29, 913 (2009)

[30] Derby B, Reis N, Seerden KAM, Grant PS, Evans JRG, MRS Online Proceedings Library Archive, 625, 195 (2000).

[31] Reis N, Derby B, MRS Online Proceedings Library Archive, 625, 117 (2000).