Journal of Industrial and Engineering Chemistry, Vol.80, 53-64, December, 2019
Carbon-coated Mg-Al layered double oxide nanosheets with enhanced removal of hexavalent chromium
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Carbon-coated Mg-Al layered double oxide (MgAl@C LDO) nanosheets were synthesized for the removal of hexavalent chromium (Cr(VI)) ions. Carbon coating could enhance the sorption capacity of Mg5Al1 LDO for the Cr(VI) removal. The sorption capacity of Mg5Al1@C LDO increased and then decreased with an increase in carbon-coated content, of which the Mg5Al1@C-2 with a carbon thickness of around 5.0 nm exhibited the best sorption capacity. The sorption behaviors of Mg5Al1@C-2 was explained by Langmuir sorption model, pseudo-second-order model, Weber-Morris model, and Boyd kinetic model. Mg5Al1@C-2 for Cr(VI) removal was a spontaneous, endothermic, and chemisorption process.
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