Catalytic properties of barium modified Ru/MgZrO2 for the isomerization linoleic acid to conjugated linoleic acid

Jiebo Chen; Lu Wang; Peng Wang; Jihong Cai

Journal of Industrial and Engineering Chemistry, Vol.80, 425-430, December, 2019

DOI10.1016/j.jiec.2019.08.022 Export Citation

Catalytic properties of barium modified Ru/MgZrO2 for the isomerization linoleic acid to conjugated linoleic acid

Jiebo Chen^†, Lu Wang, Peng Wang¹, and Jihong Cai

National Engineering Research Center for Sugarcane, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
¹College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China

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A series of Ru-MgZrO2 catalysts modified by barium were prepared by a facile impregnation method. The structure and properties of the catalysts were characterized by means of HRTEM, XPS, XRD, CO2-TPD and H2-TPR. The hydrogen-free isomerization reaction process with high catalytic activity and low saponification was achieved by controlling the basicity of the catalyst. The key role of Ba in catalysis was also discussed. The conjugated linoleic acid yield reached 85% when the Ba content was 0.5%, and the catalytic products were mainly three kinds of isomers with biological activity.

Keywords:Ruthenium;Compound oxide;Ba modified;Conjugated linoleic acid

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[2] Bernas A, Laukkanen P, Kumar N, Maki-Arvela P, Vayrynen J, Laine E, Holmbom B, Salmi T, Murzin DY, J. Catal., 210(2), 354 (2002)

[3] Sluijs I, Plantinga Y, De RB, Mennen LI, Bots ML, Am.J. Clin.Nutr., 91, 175 (2010)

[4] Shen W, Chuang CC, Martinez K, Reid T, Brown JM, Xi L, Hixson L, Hopkins R, Starnes J, Mcintosh M, J. Lipid Res., 54, 909 (2013)

[5] Coakley M, Johnson MC, Mcgrath E, Rahman S, Ross RP, Fitzgerald GF, Devery R, Stanton C, Nutr. Cancer, 56, 95 (2006)

[6] Whigham LD, Cook ME, Atkinson RL, Pharmacol. Res., 42, 503 (2000)

[7] Bernas A, Maki-Arvela P, Kumar N, Holmbom B, Salmi T, Murzin DY, Ind. Eng. Chem. Res., 42(4), 718 (2003)

[8] Pakdeechanuan P, Intarapichet KO, Fernando LN, Grun IU, J. Agr. Food Chem., 53, 923 (2005)

[9] Bernas A, Kumar N, Laukkanen P, Vayrynen J, Salmi T, Murzin DY, Appl. Catal. A: Gen., 267(1-2), 121 (2004)

[10] Philippaerts A, Goossens S, Vermandel W, Tromp M, Turner S, Geboers J, Van TG, Jacobs PA, Sels BF, Chemsuschem, 4, 684 (2011)

[11] Chen J, Chen X, Zheng Y, Li Q, RSC Adv., 5, 20248 (2015)

[12] Chen J, Zhang L, Zheng X, Zheng Y, RSC Adv., 7, 54747 (2017)

[13] Lin J, Wang Z, Zhang L, Jun NI, Rong W, Wei K, Chinese J. Catal., 33, 1075 (2012)

[14] Yang XL, Xia CG, Tang LP, Xiong XM, Mu XY, Hu B, Acta Phys. Chim. Sin., 26(1-4), 3263 (2010)

[15] Yang WS, Liu QG, Qiu WH, Lu SG, Yang LL, Solid State Ion., 121(1-4), 79 (1999)

[16] Edison TNJI, Atchudan R, Lee YR, Int. J. Hydrog. Energy, 44(4), 2323 (2019)

[17] Zhu X, Wu D, Wang W, Tan F, Wong PK, Wang X, Qiu X, Qiao X, J. Alloy. Compd., 684, 282 (2016)

[18] Wei S, Zhao Y, Fan G, Yang L, Li F, Chem. Eng. J., 322, 234 (2017)

[19] Zhang Y, Xie B, Zhang R, New J. Chem., 42, 1585 (2017)

[20] Puriwat J, Chaitree W, Suriye K, Dokjampa S, Praserthdam P, Panpranot J, Catal. Commun., 12, 80 (2011)

[21] Xiao YH, Zheng XH, Chen XH, Jiang LL, Zheng Y, Ind. Eng. Chem. Res., 56(7), 1687 (2017)

[22] Zheng X, Li Y, Zhang L, Shen L, Xiao Y, Zhang Y, Au C, Jiang L, Appl. Catal. B: Environ., 252, 98 (2019)

[23] Chen J, Zheng Y, Lin W, Zhang L, Cai Z, Chin. J. Struct. Chem., 36, 522 (2017)

[24] Zheng XH, Chen XH, Chen JB, Zheng Y, Jiang LL, Chem. Eng. J., 297, 148 (2016)

[25] Ballarini A, Benito P, Fornasari G, Scelza O, Vaccari A, Int. J. Hydrog. Energy, 38(35), 15128 (2013)

[26] Yang Z, Guo W, Lin J, Liao D, Chinese J. Catal., 27, 378 (2006)

[27] Shen LJ, Zheng XH, Lei GC, Li X, Cao YN, Jiang LL, Chem. Eng. J., 346, 238 (2018)

[28] Santra C, Rahman S, Bojja S, James OO, Sen D, Maity S, Mohanty AK, Mazumder S, Chowdhury B, Catal. Sci. Technol., 3, 360 (2013)

[29] Dai NN, Wang ZH, Jiang TZ, Feng J, Sun W, Qiao JS, Rooney D, Sun KN, J. Power Sources, 268, 176 (2014)

[30] Li DL, Li RL, Lu MM, Lin XY, Zhan YY, Jiang LL, Appl. Catal. B: Environ., 200, 566 (2017)

[31] Zhou Y, Lan G, Zhou B, Jiang W, Han W, Liu H, Ying LI, Chinese J. Catal., 34, 1395 (2013)

[32] Wang F, Zhang S, Li C, Liu J, He S, Zhao Y, Yan H, Wei M, Evans DG, Duan X, RSC Adv., 4, 10834 (2014)

[33] Berdeaux VO, Voinot L, Angioni E, Juaneda P, Sebedi J, J. Am. Oil Chem. Soc., 75, 1749 (1998)

[34] Deshpande V, Gadkari R, Mukesh D, Narasimhan C, J. Am. Oil Chem. Soc., 62, 734 (1985)

[35] Bernas A, Kumar N, Maki-Arvela P, Holmbom B, Salmi T, Murzin DY, Org. Process. Res. Dev., 8, 341 (2004)

[36] Bernas A, Kumar N, Maki-Arvela P, Kul'kova NV, Holmbom B, Salmi T, Murzin DY, Appl. Catal. A: Gen., 245(2), 257 (2003)

[37] Kreich M, Claus P, Angew. Chem.-Int. Edit., 44, 7800 (2005)

[38] Simakova OA, Leino AR, Campo B, Maki-Arvela P, Kordas K, Mikkola JP, Murzin DY, Catal. Today, 150(1-2), 32 (2010)