화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.11, 1061-1070, November, 2019
DOI10.1007/s13233-019-7176-3  Export Citation
Stimuli-Responsive Graphene Oxide-Polymer Nanocomposites
Qi Lu, Hyo Seon Jang, Wen Jiao Han, Jin Hyun Lee1, †, and Hyoung Jin Choi†
  • Department of Polymer Science and Engineering, Inha University, Incheon 22212, Korea
  • 1Polymer Research Center, Inha University, Incheon 22212, Korea
E-mail:,
Graphene oxide (GO) attracts tremendous attention for application in high-performance stimuli-responsive “smart” materials because of its unique and excellent electrical, mechanical, thermal, and optical properties, high biocompatibility, and potential application in a variety of fields, including nanocomposite-based devices. Even at an extremely small loading, the chemical, physical, and mechanical properties of GO-polymer nanocomposites can be significantly changed due to its one-atom thickness and large surface area. Therefore, GO-based filler-containing polymer nanocomposites are sensitive to various external stimuli, such as electric and magnetic fields, pH, thermal or optical excitations, and stress. This article reviews the compositions, preparations, and characteristics of a variety of external stimuli-responsive nanocomposites containing GO and other graphene-based fillers. Particularly, the electrorheological and magnetorheological behaviors of smart fluids are described with well-known models and relationships. Finally, various applications of GO-polymer nanocomposites are briefly presented.
Keywords:graphene;graphene oxide;electrorheological fluid;stimuli-responsive;nanocomposite
  1. Huang JC, Adv. Polym. Technol., 21(4), 299 (2002)
  2. Moniruzzaman M, Winey KI, Macromolecules, 39(16), 5194 (2006)
  3. Rao YQ, Pochan JM, Macromolecules, 40(2), 290 (2007)
  4. Dato A, Radmilovic V, Lee Z, Phillips J, Frenklach M, Nano Lett., 8, 2012 (2008)
  5. Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus MS, Kong J, Nano Lett., 9, 30 (2009)
  6. Peng EX, Todorova N, Yarovsky I, ACS Omega, 3, 11497 (2018)
  7. Reddy V, Babu KKCS, Torati SR, Eom YJ, Trung TQ, Lee NE, Kim CG, J. Ind. Eng. Chem., 63, 19 (2018)
  8. He SY, Petkovich ND, Liu KW, Qian YQ, Macosko CW, Stein A, Polymer, 110, 149 (2017)
  9. Buchsteiner A, Lerf A, Pieper J, J. Phys. Chem. B, 110(45), 22328 (2006)
  10. Stankovich S, Piner RD, Chen XQ, Wu NQ, Nguyen ST, Ruoff RS, J. Mater. Chem., 16, 155 (2006)
  11. Dreyer DR, Park SJ, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 38, 228 (2010)
  12. Winey KI, Vaia RA, MRS Bull., 32, 314 (2011)
  13. Wu J, Wen W, Sheng P, Soft Matter, 8, 11589 (2012)
  14. Tseng IH, Liao YF, Chiang JC, Tsai MH, Mater. Chem. Phys., 136(1), 247 (2012)
  15. Seiffert S, Thiele J, Abate AR, Weitz DA, J. Am. Chem. Soc., 132(18), 6606 (2010)
  16. Bauer WC, Kotar J, Cicuta P, Woodward RT, Weaverd JVM, Huck WTS, Soft Matter, 7, 4214 (2011)
  17. Marins JA, Soares BG, Silva AA, Hurtado MG, Livi S, J. Colloid Interface Sci., 405, 64 (2013)
  18. Tao R, Jiang Q, Phys. Rev. Lett., 73, 205 (1994)
  19. Kim YD, Klingenberg DJ, J. Colloid Interface Sci., 183(2), 568 (1996)
  20. Choi HJ, Jhon MS, Soft Matter, 5, 1562 (2009)
  21. Zhao XP, Yin JB, Chem. Mater., 14, 2258 (2002)
  22. Kim YD, Jung JC, Macromol. Res., 18(12), 1203 (2010)
  23. Hwang JK, Shin K, Lim HS, Cho JC, Kim JW, Suh KD, Macromol. Res., 20(4), 391 (2012)
  24. Zhang MY, Gong XQ, Wen WJ, Electrophoresis, 30(18), 3116 (2009)
  25. Choi SB, Han YM, Song HJ, Sohn JW, Choi HJ, J. Intell. Mater. Syst. Struct., 18, 1169 (2007)
  26. Nikitczuk J, Weinberg B, Mavroidis C, Smart Mater. Struct., 16, 418 (2007)
  27. Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)
  28. Soldano C, Mahmood A, Dujardin E, Carbon, 48, 2127 (2010)
  29. Chen H, Muller MB, Gilmore KJ, Wallace GG, Li D, Adv. Mater., 20(18), 3557 (2008)
  30. Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS, Nature, 442, 282 (2006)
  31. Zhang HB, Zheng WG, Yan Q, Yang Y, Wang JW, Lu ZH, Ji GY, Yu ZZ, Polymer, 51(5), 1191 (2010)
  32. Marsden AJ, Papageorgiou DH, Valles C, Liscio A, Palermo V, Bissett MA, Young RJ, Kinloch IA, 2D Mater., 5, 032003 (2018)
  33. Kalaitzidou K, Fukushima H, Drzal LT, Compos. Sci. Technol., 67, 2045 (2007)
  34. Kim H, Miura Y, Macosko CW, Chem. Mater., 22, 3441 (2010)
  35. Alekseev AM, Efimov AE, de With G, Mater. Sci. Eng., 443, 012002 (2018)
  36. Wu X, Qi S, He J, Duan G, J. Mater. Sci., 45, 483 (2009)
  37. Yoonessi M, Gaier JR, ACS Nano, 4, 7211 (2010)
  38. Chen GH, Weng WG, Wu DJ, Wu CL, Eur. Polym. J., 39, 2329 (2003)
  39. Salavagione HJ, Martinez G, Gomez MA, J. Mater. Chem., 19, 5027 (2009)
  40. Vadukumpully S, Paul J, Mahanta N, Valiyaveettil S, Carbon, 49, 198 (2011)
  41. Du N, Zhao CY, Chen Q, Wu G, Lu R, Mater. Chem. Phys., 120(1), 167 (2010)
  42. Yan D, Zhang HB, Jia Y, Hu J, Qi XY, Zhang Z, Yu ZZ, ACS Appl. Mater. Interf., 4, 4740 (2012)
  43. Zhang WL, Liu YD, Choi HJ, Carbon, 50, 290 (2012)
  44. Cho MS, Choi HJ, Ahn WS, Langmuir, 20(1), 202 (2004)
  45. Cao YL, Choi HJ, Zhang WL, Wang BX, Hao CC, Liu JQ, Compos. Sci. Technol., 122, 36 (2016)
  46. Sim B, Zhang WL, Choi HJ, Mater. Chem. Phys., 153, 443 (2015)
  47. Tang MY, Wang XR, Wu F, Liu Y, Zhang S, Pang XB, Li XX, Qiu HX, Carbon, 71, 238 (2014)
  48. Kim JM, Cote LJ, Kim F, Yuan W, Shull KR, Huang JX, J. Am. Ceram. Soc., 132, 8180 (2010)
  49. Kim SD, Zhang WL, Choi HJ, J. Mater. Chem. C, 2, 7541 (2014)
  50. Min TH, Choi HJ, Macromol. Res., 25(6), 565 (2017)
  51. Lee CJ, Choi HJ, Colloids Surf. A: Physicochem. Eng. Asp., 550, 56 (2018)
  52. Zhang WL, Choi HJ, Seo YS, Macromol. Chem. Phys., 214, 1415 (2013)
  53. Zhang K, Zhang WL, Choi HJ, Colloid Polym. Sci., 291, 955 (2012)
  54. Chen P, Cheng Q, Wang LM, Liu YD, Choi HJ, J. Ind. Eng. Chem., 69, 106 (2019)
  55. Yalcintas M, Dai H, Smart Mater. Struct., 8, 560 (1999)
  56. Zhang K, Li HT, Dong YZ, Zhang HL, Zhao W, Zhao SQ, Choi HJ, Polymer, 168, 29 (2019)
  57. Cho MS, Choi HJ, Jhon MS, Polymer, 46(25), 11484 (2005)
  58. Min TH, Lee CJ, Choi HJ, Polym. Test, 66, 195 (2018)
  59. Zhang WL, Choi HJ, Seo Y, Macromol. Chem. Phys., 214, 1415 (2013)
  60. Cole KS, Cole RH, J. Chem. Phys., 9, 341 (1941)
  61. Tang T, Liu F, Liu Y, Li X, Xu Q, Feng Q, Tang N, Du Y, Appl. Phys. Lett., 104, 123104 (2014)
  62. Ning G, Xu C, Hao L, Kazakova O, Fun Z, Wang H, Wang K, Gao J, Qian W, Wei F, Carbon, 51, 390 (2013)
  63. Qin S, Guo X, Cao Y, Ni Z, Xu Q, Carbon, 78, 559 (2014)
  64. Cong HP, He JJ, Lu Y, Yu SH, Small, 6, 169 (2010)
  65. Yang XY, Zhang XY, Ma YF, Huang Y, Wang YS, Chen YS, J. Mater. Chem., 19, 2710 (2009)
  66. Zhang WL, Tian Y, Liu YD, Song ZQ, Liu JQ, Choi HJ, RSC Adv., 6, 77925 (2016)
  67. Hong CH, Kim MW, Zhang WL, Moon IJ, Choi HJ, J. Colloid Interface Sci., 481, 194 (2016)
  68. Lee SH, Jung JH, Oh IK, Small, 10, 3880 (2014)
  69. Zhu I, Andres CM, Xu JD, Ramamoorthy A, Tsotsis T, Kotov NA, ACS Nano, 6, 8357 (2012)
  70. Yang H, Paek K, Kim BJ, Nanoscale, 5, 5720 (2013)
  71. Lee JH, Yang HS, Park CH, Cho HH, Yun HS, Kim BJ, Chem. Mater., 28, 3446 (2016)
  72. Qiu L, Liu DY, Wang YF, Cheng C, Zhou K, Ding J, Truong VT, Li D, Adv. Mater., 26(20), 3333 (2014)
  73. Wang DM, Duan HC, Lu JH, Lu CL, J. Mater. Chem. A, 5, 5088 (2017)
  74. Ganguli S, Roy AK, Anderson DP, Carbon, 46, 806 (2008)
  75. Yu A, Ramesh P, Itkis ME, Bekyarova E, Haddon RC, J. Phys. Chem. C, 111, 7565 (2007)
  76. Yu AP, Ramesh P, Sun XB, Bekyarova E, Itkis ME, Haddon RC, Adv. Mater., 20(24), 4740 (2008)
  77. Lin W, Zhang R, Wong CP, J. Electron. Mater., 39, 268 (2010)
  78. Veca LM, Meziani MJ, Wang W, Wang X, Lu FS, Zhang PY, Lin Y, Fee R, Connell JW, Sun YP, Adv. Mater., 21(20), 2088 (2009)
  79. Fang M, Wang KG, Lu HB, Yanga YL, Nutt S, J. Mater. Chem., 19, 7098 (2009)
  80. Acik M, Lee G, Mattevi C, Chhowalla M, Cho K, Chabal YJ, Nat. Mater., 9(10), 840 (2010)
  81. Liang JJ, Xu YF, Huang Y, Zhang L, Wang Y, Ma TF, Li FF, Guo TY, Chen YS, J. Phys. Chem. C, 113, 9921 (2009)
  82. Loomis J, King B, Panchapakesan B, Appl. Phys. Lett., 100, 073108 (2012)
  83. Loomis J, Fan XM, Khosravi F, Xu P, Fletcher M, Cohn RW, Panchapakesan B, Sci. Rep., 3, 1900 (2013)
  84. Muralidharan MN, Ansari S, Adv. Mater. Lett., 4, 927 (2013)
  85. Cheng ZX, Wang TJ, Li X, Zhang YH, Yu HF, ACS Appl. Mater. Interf., 7, 27494 (2015)
  86. Yu L, Yu H, ACS Appl. Mater. Interf., 7, 3834 (2015)
  87. Weissleder R, Nat. Biotechnol., 19, 316 (2001)
  88. Kim H, Lee D, Kim J, Kim TI, Kim WJ, ACS Nano, 7, 6735 (2013)
  89. Sakhaee-Pour A, Ahmadian MT, Vafai A, Solid State Commun., 147, 336 (2008)
  90. Choi SM, Jhi SH, Son YW, Nano Lett., 10, 3486 (2010)
  91. Cocco G, Cadelano E, Colombo L, Phys. Rev. B, 81, 241412 (2010)
  92. Lu Y, Guo J, Nano Res., 3, 189 (2009)
  93. Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH, Nature, 457, 706 (2009)
  94. Lee YB, Bae SK, Jang H, Jang SJ, Zhu SE, Sim SH, Song YI, Hong BH, Ahn JH, Nano Lett., 10, 490 (2010)
  95. Gomez-Navarro C, Burghard M, Kern K, Nano Lett., 8, 2045 (2008)
  96. Fornes TD, Paul DR, Polymer, 44(17), 4993 (2003)
  97. Zhong H, Lukes JR, Phys. Rev. B, 74, 125403 (2006)
  98. Pollack GL, Rev. Mod. Phys., 41, 48 (1969)
  99. Shenogina N, Godawat R, Keblinski P, Garde S, Phys. Rev. Lett., 102, 156101 (2009)
  100. Shenogin S, Bodapati A, Xue L, Ozisik R, Keblinski P, Appl. Phys. Lett., 85, 2229 (2004)
  101. Chen GH, Wu DJ, Weng WG, Yan WL, J. Appl. Polym. Sci., 82(10), 2506 (2001)
  102. Chen GH, Wu DJ, Weng WG, Yan WL, Polym. Eng. Sci., 41(12), 2148 (2001)
  103. Du XS, Xiao M, Meng YZ, Hay AS, Polymer, 45(19), 6713 (2004)
  104. She Y, Chen G, Wu D, Polym. Int., 56, 679 (2007)
  105. Wang WP, Pan CY, Polymer, 45(12), 3987 (2004)
  106. Kocak G, Tuncer C, Butun V, Polym. Chem., 8, 144 (2017)
  107. Shih CJ, Lin SC, Sharma R, Strano MS, Blankschtein D, Langmuir, 28(1), 235 (2012)
  108. Bak JM, Lee HI, Polymer, 53(22), 4955 (2012)
  109. Fang M, Long LA, Zhao WF, Wang LW, Chen GH, Langmuir, 26(22), 16771 (2010)
  110. Kavitha T, Abdi SIH, Park SY, Phys. Chem. Phys., 15, 5176 (2013)
  111. Wang CL, Li B, Niu WF, Hong SS, Saif B, Wang SB, Dong C, Shuang SM, RSC Adv., 5, 89299 (2015)
  112. Bae S, Kim H, Lee Y, Xu XF, Park JS, Zheng Y, Balakrishnan J, Lei T, Kim HR, Song YI, Kim YJ, Kim KS, Ozyilmaz B, Ahn JH, Hong BH, Iijima S, Nat. Nanotechnol., 5(8), 574 (2010)
  113. Kim H, Macosko CW, Polymer, 50(15), 3797 (2009)
  114. Gong L, Kinloch IA, Young RJ, Riaz I, Jalil R, Novoselov KS, Adv. Mater., 22(24), 2694 (2010)
  115. Li GL, Liu G, Li M, Wan D, Neoh KG, Kang ET, J. Phys. Chem. C, 114, 12742 (2010)
  116. Tien CP, Teng HS, J. Power Sources, 195(8), 2414 (2010)
  117. Wu Q, Xu YX, Yao ZY, Liu AR, Shi GQ, ACS Nano, 4, 1963 (2010)
  118. Wang DW, Li F, Zhao JP, Ren WC, Chen ZG, Tan J, Wu ZS, Lu IGGQ, Cheng HM, ACS Nano, 3, 1745 (2009)
  119. Eda G, Chhowalla M, Nano Lett., 9, 814 (2009)
  120. T. Hasan, Z. P. Sun, F. Q. Wang, F. Bonaccorso, P. H. Tan, A. G. Rozhin,, Adv. Mater., 21, 3874 (2009)
  121. Zhang W, Xu BS, Tanaka A, Koga Y, Carbon, 47, 922 (2009)
  122. Zhang WL, Liu YD, Choi HJ, Seo YS, RSC Adv., 3, 11723 (2013)
  123. Xiao X, Xie T, Cheng YT, J. Mater. Chem., 20, 3508 (2010)
  124. Kim JT, Jeong HJ, Park HC, Jeong HM, Bae SY, Kim BK, React. Funct. Polym., 88, 1 (2015)
  125. Ansari S, Giannelis EP, J. Polym. Sci. B: Polym. Phys., 47(9), 888 (2009)
  126. Pukanszky B, Fekete E, Mineral Fillers in Theroplastics, 139, 109 (1999).
  127. Kulkarni DD, Choi IJ, Singamaneni SS, Tsukruk VV, ACS Nano, 4, 4667 (2010)
  128. Williams KA, Boydston AJ, Bielawski CW, J. R. Soc. Interf., 4, 359 (2007)
  129. Jang BZ, Zhamu A, J. Mater. Sci., 43(15), 5092 (2008)