화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.36, No.12, 2104-2109, December, 2019
Facile fabrication and photocatalytic activity of Ag/AgI/rGO films
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The composite material, Ag/AgX/graphene (X=Br, Cl, I), is considered a promising photocatalyst for photocatalytic degradation of organic pollutants. Its photocatalytic activity is superior to that of the conventional TiO2 photocatalyst; the enhanced photocatalytic activity is attributed to its effective charge separation ability and wide visible light absorption. However, the Ag/AgX/graphene composite is often prepared in the powder form, limiting its widespread application. In addition, the simple fabrication of Ag/AgX/graphene composite films is highly challenging. In this study, a simple solution-based process based on meniscus-dragging deposition is demonstrated for the fabrication of Ag/AgI/rGO composite films. Uniform catalyst films with reasonable photocatalytic activities can be easily fabricated by using this microliter-scale solution process.
  1. Chook SW, Chia CH, Zakaria S, Ayob MK, Chee KL, Huang NM, Neoh HM, Lim HN, Jamal R, Rahman RMFRA, Nanoscale Res. Lett., 7, 541 (2012)
  2. Etacheri V, Michlits G, Seery MK, Hinder SJ, Pillai SC, ACS Appl. Mater. Interfaces, 5, 1663 (2013)
  3. Gelover S, Mondragon P, Jimenez A, J. Photochem. Photobiol. A-Chem., 165, 241 (2004)
  4. Motahari F, Mozdianfard MR, Soofivand F, Salavati-Niasari M, RSC Adv., 4, 27654 (2014)
  5. Peral J, Domenech X, Ollis DF, J. Chem. Technol. Biotechnol., 70(2), 117 (1997)
  6. Hashimoto K, Irie H, Fujishima A, Japanese J. Appl. Physics, 44, 8269 (2005)
  7. Chong MN, Jin B, Chow CWK, Saint C, Water Res., 44, 2997 (2010)
  8. Ni M, Leung MKH, Leung DYC, Sumathy K, Renew. Sust. Energ. Rev., 11, 401 (2007)
  9. Zhang X, Chen YL, Liu RS, Tsai DP, Reports Prog. Phys., 76, 046401 (2013)
  10. Drew K, Girishkumar G, Vinodgopal K, Kamat PV, J. Phys. Chem. B, 109(24), 11851 (2005)
  11. Wang Y, Wang F, He J, Nanoscale, 5, 11291 (2013)
  12. Chatterjee D, Patnam VR, Sikdar A, Joshi P, Misra R, Rao NN, J. Hazard. Mater., 156(1-3), 435 (2008)
  13. Ma X, Dai Y, Guo M, Huang B, ChemphysChem, 13, 2304 (2012)
  14. Zeng CY, Tian BZ, Zhang JL, J. Colloid Interface Sci., 405, 17 (2013)
  15. Wang P, Huang B, Zhang X, Qin X, Dai Y, Wang Z, Lou Z, ChemCatChem, 3, 360 (2011)
  16. Sherry LJ, Chang SH, Schatz GC, Van Duyne RP, Wiley BJ, Xia YN, Nano Lett., 5, 2034 (2005)
  17. Jensen TR, Malinsky MD, Haynes CL, Van Duyne RP, J. Phys. Chem. B, 104(45), 10549 (2000)
  18. Wang P, Huang B, Zhang X, Qin X, Jin H, Dai Y, Wang Z, Wei J, Zhan J, Wang S, Wang J, Whangbo MH, Chem. Eur. J., 15, 1821 (2009)
  19. Zhu M, Chen P, Liu M, ACS Nano, 5, 4529 (2011)
  20. Williams G, Seger B, Kamt PV, ACS Nano, 2, 1487 (2008)
  21. Meng XH, Shao X, Li HY, Yin J, Wang J, Liu FZ, Liu XH, Wang M, Zhong HL, Mater. Lett., 105, 162 (2013)
  22. Xiang Q, Yu J, Jaroniec M, Chem. Soc. Rev., 41, 782 (2012)
  23. Luo G, Jiang X, Li M, Shen Q, Zhang L, Yu H, ACS Appl. Mater. Interfaces, 5, 2161 (2013)
  24. Han L, Xu Z, Wang P, Dong S, Chem. Commun., 49, 4953 (2013)
  25. Xiang Q, Yu J, Jaroniec M, Chem. Commun., 47, 4532 (2011)
  26. Zhou J, Cheng Y, Yu J, J. Photochem. Photobiol. A-Chem., 223, 82 (2011)
  27. Ghosh S, Saraswathi A, Indi SS, Hoti SL, Vasan HN, Langmuir, 28(22), 8550 (2012)
  28. Ko YU, Cho SR, Choi KS, Park Y, Kim ST, Kim NH, Kim SY, Chang ST, J. Mater. Chem., 22, 3606 (2012)
  29. Ko Y, Kim NH, Lee NR, Chang ST, Carbon, 77, 964 (2014)
  30. Kim NH, Ko Y, Cho SR, Chang ST, J. Nanosci. Nanotechnol., 14, 3774 (2014)
  31. Yin Z, Song SK, You DJ, Ko Y, Cho S, Yoo J, Park SY, Piao Y, Chang ST, Kim YS, Small, 11, 4576 (2015)
  32. Ko Y, Song SK, Kim NH, Chang ST, Langmuir, 32(1), 366 (2016)
  33. Kim NH, Kim BJ, Ko Y, Cho JH, Chang ST, Adv. Mater., 25(6), 894 (2013)
  34. Liang YH, Wang H, Liu L, Wu PF, Cui WQ, McEvoy J, Zhang ZS, J. Mater. Sci., 50(21), 6935 (2015)
  35. Noguez C, J. Phys. Chem. C, 111, 3606 (2007)
  36. Ye J, Wen F, Sobhani H, Lassiter JB, Van Dorpe P, Nordlander P, Halas NJ, Nano Lett., 12, 1660 (2012)
  37. Liang H, Tian H, McCreery RL, Appl. Spectrosc., 61, 613 (2007)
  38. Zamostny P, Belohlav Z, Appl. Catal. A: Gen., 225(1-2), 291 (2002)
  39. Rashed MN, El-Amin AA, Int. J. Phys. Sci., 2, 73 (2007)
  40. Tabata S, Ohnishi H, Yagasaki E, Ippommatsu M, Domen K, Catal. Lett., 28(2-4), 417 (1994)
  41. Nosaka Y, Nosaka AY, J. Phys. Chem. C, 122, 28748 (2018)
  42. Ren ML, Chen J, Wang PF, Hou J, Qian J, Wang C, Ao YH, J. Colloid Interface Sci., 532, 190 (2018)
  43. Hu C, Peng TW, Hu XX, Nie YL, Zhou XF, Qu JH, He H, J. Am. Chem. Soc., 132(2), 857 (2010)
  44. Reddy DA, Lee S, Choi J, Park S, Ma R, Yang H, Kim TK, Appl. Surf. Sci., 341, 175 (2015)
  45. Vinoth R, Karthik P, Muthamizhchelvan C, Neppolian B, Ashokkumar M, Phys. Chem. Chem. Phys., 18, 5179 (2016)
  46. Zheng F, Xu WL, Jin HD, Hao XT, Ghiggino KP, RSC Adv., 5, 89515 (2015)
  47. Zhang X, Chen YL, Liu RS, Tsai DP, Rep. Prog. Phys., 76, 046401 (2013)