화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.81, 440-450, January, 2020
DOI10.1016/j.jiec.2019.09.034  Export Citation
Effect of vanadia loading on acidic and redox properties of VOx/TiO2 for the simultaneous abatement of PCDD/Fs and NOx
M. Gallastegi-Villa, A. Aranzabal†, M.P. González-Marcos, B.A. Markaide-Aiastui, J.A. González-Marcos, and J.R. González-Velasco
  • Group “Chemical Technologies for Environmental Sustainability”, Chemical Engineering Dept., Faculty of Science and Technology, Universidad del País Vasco, UPV/EHU, P.O. Box 644, E-48080, Bilbao, Spain
E-mail:
The effect of vanadia loading on the acidic and redox properties of VOx/TiO2 catalyst and their role in the simultaneous reduction of NO with NH3 and oxidation of o-DCB is studied. Catalyst samples with different proportions of VOx species, ranging from monomerics to V2O5 octahedral crystals have been prepared. A relationship between VOx species and their acidic and redox properties was found. At low temperature, o-DCB is adsorbed mainly on Lewis sites, associated to monomeric species, but at high temperature, o-DCB and NH3 compete for Brønsted sites associated to polymeric species.
Keywords:VOx/TiO2;Acid;Redox;NO;o-dichlorobenzene
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