Journal of the American Chemical Society, Vol.119, No.14, 3383-3384, 1997
C-13 Kinetic Isotope Effects for the Addition of Lithium Dibutylcuprate to Cyclohexenone - Reductive Elimination Is Rate-Determining
Keywords:CONJUGATE ADDITION;1;4-ADDITION REACTIONS;ORGANOCOPPER REAGENTS;CARBONYL-COMPOUNDS;ELECTRON-TRANSFER;DIMETHYLCUPRATE;MECHANISM;COMPLEXES;ALPHA;BETA-ENONES;EQUILIBRIUM