CdS/Zn2GeO4(CG) composites were synthesized through the simple hydrothermal process. The crystal structure, morphology and light absorption property of the products were studied in detail. The CG composites showed excellent photocatalytic hydrogen production performance upon visible light illumination. Especially, the CG-3 composite displayed the highest H-2 evolution rate of 1719.8 mu mol h(-1) g(-1), which was about 3.80 and 4.28 times higher than the pure CdS and Zn2GeO4. Besides, the cyclic stability of the CG-3 composite was also excellent. The PL, photocurrent response and EIS spectra results testified that the efficient separation and transfer of photoinduced charge carriers achieved between CdS and Zn2GeO4, which could result in the promotion of photocatalytic performance. Moreover, a possible mechanism of H-2 generation over CdS/Zn2GeO4 heterojunction was dis- cussed. The practicable way to construct heterojunction composites would be helpful for the design of other systems with excellent photocatalytic property. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.