The selective electrochemical reduction of CO2 to CO in water by a Re(tBu-bpy)(CO)(3)Cl catalyst incorporated into multi-walled carbon nanotubes (MWCNT) was investigated. Current densities of similar to 4 mA/cm(2) and selectivities (FECO) of 99% were achieved at -0.56 V vs RHE in CO2-saturated aqueous KHCO3 solutions. The Re(tBu-bpy)(CO)(3)Cl catalyst has been widely studied as a homogeneous catalyst in organic solvents. Supporting Re(tBu-bpy)(CO)(3)Cl on MVVCNTs increases current densities, decreases overpotential, retains selectivity for reduction of CO2 to CO, and allows operation in water at pH = 7.3 compared to the molecular catalyst in acetonitrile solution. The Re/MWCNT electrocatalysts achieve TON > 5600 and TOF > 1.6 s(-1). This electrocatalyst material is efficient, robust, simple to prepare, and scalable.