화학공학소재연구정보센터
Solar Energy, Vol.193, 494-501, 2019
High-efficiency n-type silicon PERT bifacial solar cells with selective emitters and poly-Si based passivating contacts
Bifacial crystalline silicon (c-Si) solar cells have currently attracted much attention due to the front high-efficiency and additional gain of power generation from the back side. Here, we have presented n-type passivated emitter and rear totally-diffused (n-PERT) bifacial c-Si solar cells featuring front selective emitter (SE) and polysilicon (poly-Si) based passivating contacts. The SE formation was scanned with laser doping based on front boron-diffusion p(+) emitter. The poly-Si based passivating contacts consisting of nano-layer SiOx of similar to 1.5 nm thickness grown with cost-effective nitric acid oxidation and phosphorus-doped polysilicon exhibited excellent passivation for high open-circuit voltage. We have successfully achieved the large-area (156 x 156 mm(2)) n-PERT bifacial solar cells yielding top efficiency of 21.15%, together with a promising short-circuit current density of 40.40 mA/cm(2). Theoretical calculation has further demonstrated that the optimal thickness of SiOx nano-layer will increase from 1.5 nm to 1.8 nm if the density of interface defect state decreases by one magnitude from 1 x 10(10) cm(-2)/eV, and the cell efficiency can be improved up to 24.64% with open-circuit voltage over 0.720 V by optimizing the parameters of functional materials and interface layers. The present work has indicated that the commercialization of low-cost and high-efficiency n-PERT bifacial c-Si cells is possible due to the processes compatible with existing production lines.