Lewis acid catalysts stable in water. Correlation between catalytic activity in water and hydrolysis constants and exchange rate constants for substitution of inner-sphere water ligands

Kobayashi S; Nagayama S; Busujima T

Journal of the American Chemical Society, Vol.120, No.32, 8287-8288, 1998

Kobayashi S, Nagayama S, Busujima T

Keywords:SILYL ENOL ETHERS;SCANDIUM TRIFLUOROMETHANESULFONATE SC(OTF)3;COMMERCIAL FORMALDEHYDE SOLUTION;DIELS-ALDER REACTION;AQUEOUS-MEDIA;ALLYLATION REACTIONS;CARBONYL-COMPOUNDS;ORGANOMETALLIC REAGENT;MICELLAR SYSTEMS;ALDOL REACTIONS