화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.82, 290-302, February, 2020
DOI10.1016/j.jiec.2019.10.025  Export Citation
Corrosion resistance of epoxy coating on mild steel through polyamidoamine dendrimer-covalently functionalized graphene oxide nanosheets
Mohammad Ramezanzadeh, Bahram Ramezanzadeh†, Morteza Ganjaee Sari1, and Mohammad Reza Saeb2
  • Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
  • 1Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology (ICST), PO Box: 16765-654, Tehran, Iran
  • 2Department of Resin and Additives, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
E-mail:
Epoxy coating was reinforced with polyamidoamine dendrimer-reduced graphene oxide nanosheets (GO-PAMAM) to obtain a high-performance anti-corrosion system. The GO-PAMAM was characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and UV-vis analysis. Results confirmed that PAMAM molecules successfully grafted on the GO surface, resulting in the lamellae d-spacing increment. Results of electrochemical impedance spectroscopy (EIS) and salt spray test evidenced that in the presence of 0.2 wt.% GO-PAMAM the epoxy coating corrosion protection properties were effectively enhanced. It was found from the results that the PAMAM could enhance the GO particle dispersion in the epoxy through increasing the GO nanosheets interlayer space and surface hydrophilic nature reduction.
Keywords:Corrosion resistance;Reduced graphene oxide nanosheets;Epoxy nanocomposite;Polyamidoamine dendrimer;Covalent functionalization;XPS
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