아크릴산을 이용한 폴리옥시에틸렌계 반응성 계면활성제의 합성 및 수성 점착제 특성

조정은; 이상철; 박종권; 김경실; 신혜린; 김유리; 정노희; Jung-Eun Cho; Sang-Chul Lee; Jong-Kwon Park; Kyung-Sil Kim; Hye-Lin Shin; Yu-Ri Kim; Noh-Hee Jeong

Polymer(Korea), Vol.44, No.1, 6-12, January, 2020

DOI10.7317/pk.2020.44.1.6 Export Citation

아크릴산을 이용한 폴리옥시에틸렌계 반응성 계면활성제의 합성 및 수성 점착제 특성

Synthesis of Polyoxyethylene Reactive Surfactant Using Acrylic Acid and Properties of Water-based Adhesive

조정은, 이상철¹, 박종권¹, 김경실¹, 신혜린, 김유리¹, 정노희^†

충북대학교 공과대학 공업화학과
¹대양포리졸

Jung-Eun Cho, Sang-Chul Lee¹, Jong-Kwon Park¹, Kyung-Sil Kim¹, Hye-Lin Shin, Yu-Ri Kim¹, and Noh-Hee Jeong^†

Dept. of Engineering Chemistry, Chungbuk National University, Cheongju 28644, Korea
¹Daeyang Polysol Co., LTD, Sandanro 87, Heungdeok-gu, Cheongju 28577, Korea

E-mail:

초록

실험에서 반응성 계면활성제는 비이온성 계면활성제인 polyoxyethylene lauryl ether(C12POE23), polyoxy-ethylene stearyl ether(C18POE20) 및 아크릴산을 사용하여 합성하였다. 합성한 계면활성제는 FTIR 및 1H NMR에 의해 확인하였으며, 물성은 임계미셀농도와 유화력을 측정하였다. 합성한 반응성 계면활성제의 표면장력 및 임계미셀농도는 polyoxyethylene lauryl ether acrylate(C12POE23-AA)에 대해 1.1×10-4 mol/L 및 37.85 dyne/cm이고 polyoxyethylene stearyl ether acrylate(C18POE20-AA)에 대해서는 9.6×10-5 mol/L, 39.88 dyne/cm이었다. 본 연구에서 합성된 반응성 계면활성제를 점착제의 유화 중합에서 유화제로 사용하여 그 물성을 평가하였다. 고형분 함량은 57.2~57.5%의 범위에서 측정되었다. 초기 접착의 경우, 반응성 유화제로 ??제조된 C12POE23-AA는 #11으로 측정되었고, C18POE20-AA는 #9이다. 반응성 유화제를 이용한 수성 점착제는 피부용 점착제로서 응용될 것이다

In this experiment, reactive surfactants were synthesized by using nonionic surfactants such as polyoxyethylene lauryl ether (C12POE23), polyoxyethylene stearyl ether (C18POE20) and acrylic acid. The synthesized surfactant was confirmed by FTIR and 1H NMR. In addition, its surface tension and emulsifying properties were estimated. The surface tension and critical micelle concentration of the synthesized reactive surfactant were 1.1×10-4 mol/L and 37.85 dyne/cm, respectively, for polyoxyethylene lauryl ether acrylate (C12POE23-AA) and 9.6×10-5 mol/L and 39.88 dyne/cm, respectively, for polyoxyethylene stearyl ether acrylate (C18POE20-AA). The synthesized reactive surfactant in this research was used as an emulsifier in emulsion polymerization of adhesives and its physical properties were evaluated. The solid content was measured in the range of 57.2~57.5%. In the case of initial adhesion, the C12POE23-AA and C18POE20-AA made with reactive emulsifier showed #11 and #9, respectively. Water-based adhesive using a reactive emulsifier will be applied as an adhesive for skin

Keywords:reactive surfactants;polyoxyethylene nonionic surfactants;critical micelle concentration;pressure sensitive adhesive;solids content

[References]

Dufour M, Guyot A, Colloid Polym. Sci., 281, 97 (2003)
Chern CS, Chen TJ, Colloid Polym. Sci., 275, 546 (1997)
Yao R, Qian J, Li H, Yasin A, Xie Y, Yang H, RSC Adv., 4, 2865 (2014)
Pelton R, Flaherty T, Polym. Int., 52, 479 (2003)
Kirkpatrick FH, Sandberg H, Biochim. Biophys. Acta(BBA)- Biomembranes, 298, 209 (1973).
Shen YH, Chemosphere, 44, 989 (2001)
Paraknowitsch JP, Zhang Y, Thomas A, J. Mater. Chem., 21, 15537 (2011)
Kattimuttathu S, Foerst G, Schubert R, Bartsch E, J. Surfact. Deterg., 15, 207 (2012)
Santra S, Tapec R, Theodoropoulou N, Dobson J, Hebard A, Tan WH, Langmuir, 17(10), 2900 (2001)
Aubrey DW, Welding GN, Wong T, J. Appl. Polym., 13, 2193 (1969)
Czech Z, Polym. Int., 52, 347 (2003)
Crosby AJ, Shull KR, Polym. Phys., 37, 3455 (1999)
Udagama R, Degrandi-Contraires E, Creton C, Graillat C, McKenna TFL, Bourgeat-Lami E, Macromolecules, 44(8), 2632 (2011)
Leong YC, Lee LM, Gan SN, J. Appl. Polym., 88, 2118 (2003)
Sasaki M, Fujita K, Adachi m, Fujii S, Nakamura Y, Urahama Y, Int. J. Adhes. Adhes., 28, 372 (2008)
Kraus G, Rollmann KW, J. Appl. Polym., 21, 3311 (1977)
Christensen SF, Everland H, Hassager O, Almdal K, Int. J. Adhes. Adhes., 18, 131 (1998)
Minghetti P, Cilurzo F, Tosi L, Casiraghi a, Montanari L, AAPS PharmSciTech., 4, 53 (2003)
Toyama M, Ito T, Nukatsuka H, Ikeda M, J. Appl. Polym., 17, 3495 (1973)
Amalvy JI, Unzue MJ, Schoonbrood HAS, Asua JM, J. Polym. Sci., 40, 2994 (2002)
Pasquali RC, Sacco N, Bregni C, Lat. Am. J. Pharm., 28, 313 (2009)
Lee SC, Jeong NH, Appl. Chem. Eng., 30(3), 352 (2019)
Son HC, Kim HG, Lee DH, Min KE, Polym. Korea, 32, 313 (2008)

[Referenced By]

[1] Dufour M, Guyot A, Colloid Polym. Sci., 281, 97 (2003)

[2] Chern CS, Chen TJ, Colloid Polym. Sci., 275, 546 (1997)

[3] Yao R, Qian J, Li H, Yasin A, Xie Y, Yang H, RSC Adv., 4, 2865 (2014)

[4] Pelton R, Flaherty T, Polym. Int., 52, 479 (2003)

[5] Kirkpatrick FH, Sandberg H, Biochim. Biophys. Acta(BBA)- Biomembranes, 298, 209 (1973).

[6] Shen YH, Chemosphere, 44, 989 (2001)

[7] Paraknowitsch JP, Zhang Y, Thomas A, J. Mater. Chem., 21, 15537 (2011)

[8] Kattimuttathu S, Foerst G, Schubert R, Bartsch E, J. Surfact. Deterg., 15, 207 (2012)

[9] Santra S, Tapec R, Theodoropoulou N, Dobson J, Hebard A, Tan WH, Langmuir, 17(10), 2900 (2001)

[10] Aubrey DW, Welding GN, Wong T, J. Appl. Polym., 13, 2193 (1969)

[11] Czech Z, Polym. Int., 52, 347 (2003)

[12] Crosby AJ, Shull KR, Polym. Phys., 37, 3455 (1999)

[13] Udagama R, Degrandi-Contraires E, Creton C, Graillat C, McKenna TFL, Bourgeat-Lami E, Macromolecules, 44(8), 2632 (2011)

[14] Leong YC, Lee LM, Gan SN, J. Appl. Polym., 88, 2118 (2003)

[15] Sasaki M, Fujita K, Adachi m, Fujii S, Nakamura Y, Urahama Y, Int. J. Adhes. Adhes., 28, 372 (2008)

[16] Kraus G, Rollmann KW, J. Appl. Polym., 21, 3311 (1977)

[17] Christensen SF, Everland H, Hassager O, Almdal K, Int. J. Adhes. Adhes., 18, 131 (1998)

[18] Minghetti P, Cilurzo F, Tosi L, Casiraghi a, Montanari L, AAPS PharmSciTech., 4, 53 (2003)

[19] Toyama M, Ito T, Nukatsuka H, Ikeda M, J. Appl. Polym., 17, 3495 (1973)

[20] Amalvy JI, Unzue MJ, Schoonbrood HAS, Asua JM, J. Polym. Sci., 40, 2994 (2002)

[21] Pasquali RC, Sacco N, Bregni C, Lat. Am. J. Pharm., 28, 313 (2009)

[22] Lee SC, Jeong NH, Appl. Chem. Eng., 30(3), 352 (2019)

[23] Son HC, Kim HG, Lee DH, Min KE, Polym. Korea, 32, 313 (2008)