Journal of the Electrochemical Society, Vol.141, No.4, 1082-1085, 1994
The Applications of Citric-Acid Hydrogen-Peroxide Etching Solutions in the Processing of Pseudomorphic MODFETs
The etching characteristics of GaAs and Al0.28Ga0.72As in citric acid/hydrogen peroxide etching solution were studied. The etch rate and the selectivity were measured over a wide concentration range from room temperature down to 0-degrees-C. The results show that by changing the concentration of the solution we can vary the selectivity (GaAs etch rate : Al0.28Ga0.72As etch rate) from over 80:1 to reverse selectivity of 1:1.4; the GaAs etch rate can also be varied from over 4000 angstrom/min to less than 150 angstrom/min. However, high selectivity process consistently shows high GaAs etch rate. We have developed mesa and gate recess etch processes for pseudomorphic modulation doped field effect transistor (MODFET) structures based on these results. Using a two-step mesa etch process, we can produce a recessed sidewall profile of the InGaAs channel layer and hence avoid the parasitic gate leakage path caused by the contact of Schottky gate to the exposed channel layer at the sidewall. A nonselective low etch rate process was chosen for gate recess etch since the selective etch shows high GaAs etch rate and causes excessive undercut in the cap layer. Using the citric acid/hydrogen peroxide etch process with low etch rate, very uniform threshold voltage (with a standard deviation of 25 mV across a 2 in. wafer) can be achieved. This is the best result reported using nonselective wet etch and compares very favorably to published results using dry etch.
Keywords:GAAS