Reactions involving reducing sugars [glucose, fructose, and invert sugar (IS)] were studied in the presence of calcium phosphate apatites (hydroxyapatite HAp and fluorapatite FAp). An absorption band at 295 nm characteristic of the alpha -dicarbonyl Ca complex was detected by W-visible analysis of the sugar solutions. The residual apatites were analyzed by X-ray diffraction and infrared spectroscopy. The first method showed that the apatitic structure is maintained, and the second detected new characteristic bands of an organic compound most certainly adsorbed onto the apatitic surface.