화학공학소재연구정보센터
Langmuir, Vol.35, No.47, 15114-15120, 2019
Influence of the Silver Nanocrystal Shape on the Luminous Efficiency of Blue-Emitting Polymer Light-Emitting Diodes
Truncated silver nanodecahedrons (TAgNDs) and truncated silver nanoplates (TAgNPs) fabricated via chemical reduction and photochemical methods were added to poly[3,4-ethylenedioxythiophene]:poly[styrenesulfonate] (PEDOT:PSS) as dopants to promote the luminous efficiency of blue -emitting polymer light-emitting diodes (PLEDs). The differences in shape between TAgNDs and TAgNPs result in better dispersion of TAgNDs in PEDOT:PSS. Therefore, at an optimal doping concentration (the distributed density in the light-emitting region is 6.88 mu g cm(-2) for TAgNDs and 5.16 mu g cm(-2) for TAgNPs), the average current efficacy and maximum electroluminescence intensity enhancement factor for TAgND-doped PLEDs were 4.18 cd A(-1) and 420%, respectively, which are much higher than those for TAgNP-doped PLEDs (1.83 cd A(-1) and 200%) at a luminescence wavelength of 440 nm.